[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
Two independent molecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclohexyl groups as well as the benzene ring. In each molecule, the Au atom is coordinated within a S, P-donor set that defines a...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720579809869824 |
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| author | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_facet | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_sort | Tadbuppa, P.P. |
| collection | UM |
| description | Two independent molecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclohexyl groups as well as the benzene ring. In each molecule, the Au atom is coordinated within a S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)degrees for the two molecules], with the distortion due in part to the close intramolecular approach of the O atom [Au center dot center dot center dot O contacts = 3.054 (4) and 3.013 (4) angstrom, respectively, for the two molecules]. |
| first_indexed | 2024-03-06T05:37:16Z |
| format | Article |
| id | um.eprints-14775 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:16Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-147752019-01-30T09:03:09Z http://eprints.um.edu.my/14775/ [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) Tadbuppa, P.P. Tiekink, E.R.T. QC Physics Two independent molecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclohexyl groups as well as the benzene ring. In each molecule, the Au atom is coordinated within a S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)degrees for the two molecules], with the distortion due in part to the close intramolecular approach of the O atom [Au center dot center dot center dot O contacts = 3.054 (4) and 3.013 (4) angstrom, respectively, for the two molecules]. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M450-U1045. ISSN 1600-5368, |
| spellingShingle | QC Physics Tadbuppa, P.P. Tiekink, E.R.T. [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_full | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_fullStr | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_full_unstemmed | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_short | [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I) |
| title_sort | z o methyl n 3 chlorophenyl thiocarbamato kappa s tricyclohexylphosphine kappa p gold i |
| topic | QC Physics |
| work_keys_str_mv | AT tadbuppapp zomethyln3chlorophenylthiocarbamatokappastricyclohexylphosphinekappapgoldi AT tiekinkert zomethyln3chlorophenylthiocarbamatokappastricyclohexylphosphinekappapgoldi |