[(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph
The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P (1) over bar) polymorph [Hall et al. (1993). Aust. J. Chem. 46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946798808399872 |
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| author | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_facet | Tadbuppa, P.P. Tiekink, E.R.T. |
| author_sort | Tadbuppa, P.P. |
| collection | UM |
| description | The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P (1) over bar) polymorph [Hall et al. (1993). Aust. J. Chem. 46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.036 (2) angstrom]. In the crystal structure, molecules are arranged into supra-molecular chains along the b axis mediated by C-H center dot center dot center dot pi interactions. |
| first_indexed | 2024-03-06T05:37:16Z |
| format | Article |
| id | um.eprints-14778 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:16Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-147782019-01-30T09:01:51Z http://eprints.um.edu.my/14778/ [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph Tadbuppa, P.P. Tiekink, E.R.T. QC Physics The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P (1) over bar) polymorph [Hall et al. (1993). Aust. J. Chem. 46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.036 (2) angstrom]. In the crystal structure, molecules are arranged into supra-molecular chains along the b axis mediated by C-H center dot center dot center dot pi interactions. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph. Acta Crystallographica Section E: Structure Reports Online, 66 (4). M402-U624. ISSN 1600-5368, |
| spellingShingle | QC Physics Tadbuppa, P.P. Tiekink, E.R.T. [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph |
| title | [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph |
| title_full | [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph |
| title_fullStr | [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph |
| title_full_unstemmed | [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph |
| title_short | [(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph |
| title_sort | z o ethyl n phenylthiocarbamato kappa s tricyclohexylphosphine kappa p gold i a monoclinic polymorph |
| topic | QC Physics |
| work_keys_str_mv | AT tadbuppapp zoethylnphenylthiocarbamatokappastricyclohexylphosphinekappapgoldiamonoclinicpolymorph AT tiekinkert zoethylnphenylthiocarbamatokappastricyclohexylphosphinekappapgoldiamonoclinicpolymorph |