4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate
The V V atom in the title compound, [V(C8H9N2O)(C17H14N2O3) O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. Two mononuclear co...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720581244321792 |
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| author | Wong, H.W. Lo, K.M. Ng, S.W. |
| author_facet | Wong, H.W. Lo, K.M. Ng, S.W. |
| author_sort | Wong, H.W. |
| collection | UM |
| description | The V V atom in the title compound, [V(C8H9N2O)(C17H14N2O3) O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds, generating a centrosymmetric aggregate. |
| first_indexed | 2024-03-06T05:37:17Z |
| format | Article |
| id | um.eprints-14782 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:17Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-147822019-01-30T08:26:23Z http://eprints.um.edu.my/14782/ 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate Wong, H.W. Lo, K.M. Ng, S.W. QC Physics The V V atom in the title compound, [V(C8H9N2O)(C17H14N2O3) O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds, generating a centrosymmetric aggregate. International Union of Crystallography 2010 Article PeerReviewed Wong, H.W. and Lo, K.M. and Ng, S.W. (2010) 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (4). M481-U1339. ISSN 1600-5368, |
| spellingShingle | QC Physics Wong, H.W. Lo, K.M. Ng, S.W. 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate |
| title | 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate |
| title_full | 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate |
| title_fullStr | 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate |
| title_full_unstemmed | 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate |
| title_short | 4-Methylbenzohydrazidato-kappa N-2 `,O)[2-(4-methylbenzoylhydrazinylidene-kappa N-2,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate |
| title_sort | 4 methylbenzohydrazidato kappa n 2 o 2 4 methylbenzoylhydrazinylidene kappa n 2 o 3 phenylpropionato 2 oxidovanadium v methanol monosolvate |
| topic | QC Physics |
| work_keys_str_mv | AT wonghw 4methylbenzohydrazidatokappan2o24methylbenzoylhydrazinylidenekappan2o3phenylpropionato2oxidovanadiumvmethanolmonosolvate AT lokm 4methylbenzohydrazidatokappan2o24methylbenzoylhydrazinylidenekappan2o3phenylpropionato2oxidovanadiumvmethanolmonosolvate AT ngsw 4methylbenzohydrazidatokappan2o24methylbenzoylhydrazinylidenekappan2o3phenylpropionato2oxidovanadiumvmethanolmonosolvate |