Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate]
In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]center dot C2H6O}(n), the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ri...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946835781189632 |
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| author | Sadeghi, O. Amini, M.M. Ng, S.W. |
| author_facet | Sadeghi, O. Amini, M.M. Ng, S.W. |
| author_sort | Sadeghi, O. |
| collection | UM |
| description | In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]center dot C2H6O}(n), the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The mu(3)-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O-H center dot center dot center dot O hydrogen bonds. |
| first_indexed | 2024-03-06T05:37:50Z |
| format | Article |
| id | um.eprints-15012 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:50Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-150122019-01-31T04:51:02Z http://eprints.um.edu.my/15012/ Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate] Sadeghi, O. Amini, M.M. Ng, S.W. QC Physics In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]center dot C2H6O}(n), the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The mu(3)-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O-H center dot center dot center dot O hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed Sadeghi, O. and Amini, M.M. and Ng, S.W. (2010) Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate]. Acta Crystallographica Section E: Structure Reports Online, 66 (3). M285-U3404. ISSN 1600-5368, |
| spellingShingle | QC Physics Sadeghi, O. Amini, M.M. Ng, S.W. Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate] |
| title | Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate] |
| title_full | Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate] |
| title_fullStr | Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate] |
| title_full_unstemmed | Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate] |
| title_short | Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate] |
| title_sort | poly mu 3 isonicotinato kappa o 3 o n triphenylphosphine kappa p silver i ethanol solvate |
| topic | QC Physics |
| work_keys_str_mv | AT sadeghio polymu3isonicotinatokappao3ontriphenylphosphinekappapsilveriethanolsolvate AT aminimm polymu3isonicotinatokappao3ontriphenylphosphinekappapsilveriethanolsolvate AT ngsw polymu3isonicotinatokappao3ontriphenylphosphinekappapsilveriethanolsolvate |