fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1)
The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-,...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946836174405632 |
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| author | Wardell, S.M.S.V. Harrison, W.T.A. Tiekink, E.R.T. de Lima, G.M. Wardell, J.L. |
| author_facet | Wardell, S.M.S.V. Harrison, W.T.A. Tiekink, E.R.T. de Lima, G.M. Wardell, J.L. |
| author_sort | Wardell, S.M.S.V. |
| collection | UM |
| description | The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds. |
| first_indexed | 2024-03-06T05:37:51Z |
| format | Article |
| id | um.eprints-15014 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:51Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-150142019-01-30T08:24:21Z http://eprints.um.edu.my/15014/ fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) Wardell, S.M.S.V. Harrison, W.T.A. Tiekink, E.R.T. de Lima, G.M. Wardell, J.L. Q Science (General) The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed Wardell, S.M.S.V. and Harrison, W.T.A. and Tiekink, E.R.T. and de Lima, G.M. and Wardell, J.L. (2010) fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1). Acta Crystallographica Section E: Structure Reports Online, 66 (3). M312-U3665. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Wardell, S.M.S.V. Harrison, W.T.A. Tiekink, E.R.T. de Lima, G.M. Wardell, J.L. fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title | fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_full | fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_fullStr | fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_full_unstemmed | fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_short | fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_sort | fac 2 amidoethyl kappa c 2 1 o aquatrichloridotin iv 1 4 7 10 13 16 hexaoxacyclooctadecane 2 1 |
| topic | Q Science (General) |
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