4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate
The title benzene hemisolvate, C17H18N2O3 center dot 0.5C(6)H(6), features an essentially planar (the r.m.s. deviation of the non-H atoms, excluding methyl-C, is 0.071 angstrom) diazo molecule with an E conformation about the N=N bond, and a half-molecule of benzene disposed about a centre of invers...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720618841014272 |
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| author | Baul, T.S.B. Paul, A. Tiekink, E.R.T. |
| author_facet | Baul, T.S.B. Paul, A. Tiekink, E.R.T. |
| author_sort | Baul, T.S.B. |
| collection | UM |
| description | The title benzene hemisolvate, C17H18N2O3 center dot 0.5C(6)H(6), features an essentially planar (the r.m.s. deviation of the non-H atoms, excluding methyl-C, is 0.071 angstrom) diazo molecule with an E conformation about the N=N bond, and a half-molecule of benzene disposed about a centre of inversion. The dihedral angle formed between the benzene rings of the diazo molecule is 7.69 (12)degrees. In the crystal, centrosymmetrically related dimers associate via the eight-membered carboxylic acid dimer synthon, {center dot center dot center dot HOC(=O)}(2), and these are connected into a supramolecular chain along the b axis via C-H center dot center dot center dot O contacts. |
| first_indexed | 2024-03-06T05:37:51Z |
| format | Article |
| id | um.eprints-15018 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:51Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-150182019-01-31T01:43:01Z http://eprints.um.edu.my/15018/ 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate Baul, T.S.B. Paul, A. Tiekink, E.R.T. Q Science (General) The title benzene hemisolvate, C17H18N2O3 center dot 0.5C(6)H(6), features an essentially planar (the r.m.s. deviation of the non-H atoms, excluding methyl-C, is 0.071 angstrom) diazo molecule with an E conformation about the N=N bond, and a half-molecule of benzene disposed about a centre of inversion. The dihedral angle formed between the benzene rings of the diazo molecule is 7.69 (12)degrees. In the crystal, centrosymmetrically related dimers associate via the eight-membered carboxylic acid dimer synthon, {center dot center dot center dot HOC(=O)}(2), and these are connected into a supramolecular chain along the b axis via C-H center dot center dot center dot O contacts. International Union of Crystallography 2010 Article PeerReviewed Baul, T.S.B. and Paul, A. and Tiekink, E.R.T. (2010) 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). O540-U4334. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Baul, T.S.B. Paul, A. Tiekink, E.R.T. 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate |
| title | 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate |
| title_full | 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate |
| title_fullStr | 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate |
| title_full_unstemmed | 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate |
| title_short | 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)-diazenyl]benzoic acid benzene hemisolvate |
| title_sort | 4 e 5 tert butyl 2 hydroxyphenyl diazenyl benzoic acid benzene hemisolvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT baultsb 4e5tertbutyl2hydroxyphenyldiazenylbenzoicacidbenzenehemisolvate AT paula 4e5tertbutyl2hydroxyphenyldiazenylbenzoicacidbenzenehemisolvate AT tiekinkert 4e5tertbutyl2hydroxyphenyldiazenylbenzoicacidbenzenehemisolvate |