Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate
The asymmetric unit of the title salt, 2C(4)H(12)NO(+)center dot C14H8O4S22-, contains an ethyl(2-hydroxy)aminium cation and half a 2,2'-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydroxy group...
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| Format: | Article |
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International Union of Crystallography
2010
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| author | Broker, G.A. Tiekink, E.R.T. |
| author_facet | Broker, G.A. Tiekink, E.R.T. |
| author_sort | Broker, G.A. |
| collection | UM |
| description | The asymmetric unit of the title salt, 2C(4)H(12)NO(+)center dot C14H8O4S22-, contains an ethyl(2-hydroxy)aminium cation and half a 2,2'-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydroxy group [the N-C-C-O torsion angle is 66.5 (2)degrees]. A twisted conformation is found for the anion [the C-S-S-C torsion angle is 91.51 (9)degrees and the dihedral angle between the rings is 81.01 (4)degrees]. A supramolecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O-H center dot center dot center dot O- and N+-H center dot center dot center dot O- hydrogen bonding. |
| first_indexed | 2024-03-06T05:37:52Z |
| format | Article |
| id | um.eprints-15021 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:37:52Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-150212019-04-16T11:42:02Z http://eprints.um.edu.my/15021/ Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate Broker, G.A. Tiekink, E.R.T. Q Science (General) The asymmetric unit of the title salt, 2C(4)H(12)NO(+)center dot C14H8O4S22-, contains an ethyl(2-hydroxy)aminium cation and half a 2,2'-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydroxy group [the N-C-C-O torsion angle is 66.5 (2)degrees]. A twisted conformation is found for the anion [the C-S-S-C torsion angle is 91.51 (9)degrees and the dihedral angle between the rings is 81.01 (4)degrees]. A supramolecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O-H center dot center dot center dot O- and N+-H center dot center dot center dot O- hydrogen bonding. International Union of Crystallography 2010 Article PeerReviewed Broker, G.A. and Tiekink, E.R.T. (2010) Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). O705-U5759. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Broker, G.A. Tiekink, E.R.T. Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate |
| title | Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate |
| title_full | Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate |
| title_fullStr | Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate |
| title_full_unstemmed | Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate |
| title_short | Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate |
| title_sort | bis ethyl 2 hydroxyethyl azanium 2 2 disulfanediyldibenzoate |
| topic | Q Science (General) |
| work_keys_str_mv | AT brokerga bisethyl2hydroxyethylazanium22disulfanediyldibenzoate AT tiekinkert bisethyl2hydroxyethylazanium22disulfanediyldibenzoate |