[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV)
The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot ce...
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International Union of Crystallography
2010
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| _version_ | 1825720646354599936 |
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| author | Lee, S.M. Ali, H.M. Lo, K.M. |
| author_facet | Lee, S.M. Ali, H.M. Lo, K.M. |
| author_sort | Lee, S.M. |
| collection | UM |
| description | The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. |
| first_indexed | 2024-03-06T05:38:17Z |
| format | Article |
| id | um.eprints-15203 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:17Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-152032019-01-29T08:57:35Z http://eprints.um.edu.my/15203/ [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) Lee, S.M. Ali, H.M. Lo, K.M. QC Physics The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. International Union of Crystallography 2010 Article PeerReviewed Lee, S.M. and Ali, H.M. and Lo, K.M. (2010) [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (2). M162-U717. ISSN 1600-5368, |
| spellingShingle | QC Physics Lee, S.M. Ali, H.M. Lo, K.M. [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
| title | [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
| title_full | [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
| title_fullStr | [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
| title_full_unstemmed | [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
| title_short | [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
| title_sort | n 5 bromo 2 oxidobenzylidene kappa o 3 hydroxy 2 naphthohydrazidato kappa n 2 o dicyclohexyltin iv |
| topic | QC Physics |
| work_keys_str_mv | AT leesm n5bromo2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2odicyclohexyltiniv AT alihm n5bromo2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2odicyclohexyltiniv AT lokm n5bromo2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2odicyclohexyltiniv |