[mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1)
In the title mixed solvate, [Au2Fe(C17H14P)(2)Cl-2]center dot CHCl3 center dot 0.5CH(3)(CH2)(4)CH3, the hexane solvent molecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P, Cl-donor sets, and when viewed down the P center dot center...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: |
| _version_ | 1796946865446453248 |
|---|---|
| author | Meyer, N. Mohr, F. Tiekink, E.R.T. |
| author_facet | Meyer, N. Mohr, F. Tiekink, E.R.T. |
| author_sort | Meyer, N. |
| collection | UM |
| description | In the title mixed solvate, [Au2Fe(C17H14P)(2)Cl-2]center dot CHCl3 center dot 0.5CH(3)(CH2)(4)CH3, the hexane solvent molecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P, Cl-donor sets, and when viewed down the P center dot center dot center dot P axis the Au atoms are gauche to each other. In the crystal structure, the chloroform solvent molecule is associated with the complex via a C-H center dot center dot center dot Cl contact, and the hexane solvent molecules occupy voids defined by the remaining components of the structure. |
| first_indexed | 2024-03-06T05:38:17Z |
| format | Article |
| id | um.eprints-15205 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:17Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-152052019-01-31T04:44:35Z http://eprints.um.edu.my/15205/ [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1) Meyer, N. Mohr, F. Tiekink, E.R.T. QC Physics In the title mixed solvate, [Au2Fe(C17H14P)(2)Cl-2]center dot CHCl3 center dot 0.5CH(3)(CH2)(4)CH3, the hexane solvent molecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P, Cl-donor sets, and when viewed down the P center dot center dot center dot P axis the Au atoms are gauche to each other. In the crystal structure, the chloroform solvent molecule is associated with the complex via a C-H center dot center dot center dot Cl contact, and the hexane solvent molecules occupy voids defined by the remaining components of the structure. International Union of Crystallography 2010 Article PeerReviewed Meyer, N. and Mohr, F. and Tiekink, E.R.T. (2010) [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1). Acta Crystallographica Section E: Structure Reports Online, 66 (2). M168-U792. ISSN 1600-5368, |
| spellingShingle | QC Physics Meyer, N. Mohr, F. Tiekink, E.R.T. [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1) |
| title | [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1) |
| title_full | [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1) |
| title_fullStr | [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1) |
| title_full_unstemmed | [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1) |
| title_short | [mu-1,1 `-Bis(diphenylphosphino)ferrocene-kappa P-2:P `]bis[chloridogold(I)]-chloroform-hexane (2/2/1) |
| title_sort | mu 1 1 bis diphenylphosphino ferrocene kappa p 2 p bis chloridogold i chloroform hexane 2 2 1 |
| topic | QC Physics |
| work_keys_str_mv | AT meyern mu11bisdiphenylphosphinoferrocenekappap2pbischloridogoldichloroformhexane221 AT mohrf mu11bisdiphenylphosphinoferrocenekappap2pbischloridogoldichloroformhexane221 AT tiekinkert mu11bisdiphenylphosphinoferrocenekappap2pbischloridogoldichloroformhexane221 |