Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
The title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (1...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946866815893504 |
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| author | Caracelli, I. Moran, P.J.S. Hinoue, L. Zukerman-Schpector, J. Tiekink, E.R.T. |
| author_facet | Caracelli, I. Moran, P.J.S. Hinoue, L. Zukerman-Schpector, J. Tiekink, E.R.T. |
| author_sort | Caracelli, I. |
| collection | UM |
| description | The title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (13)degrees, respectively] to the carbonyl and nitrophenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H center dot center dot center dot O contacts. |
| first_indexed | 2024-03-06T05:38:18Z |
| format | Article |
| id | um.eprints-15212 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:18Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-152122019-01-31T01:46:09Z http://eprints.um.edu.my/15212/ Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate Caracelli, I. Moran, P.J.S. Hinoue, L. Zukerman-Schpector, J. Tiekink, E.R.T. QC Physics The title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (13)degrees, respectively] to the carbonyl and nitrophenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H center dot center dot center dot O contacts. International Union of Crystallography 2010 Article PeerReviewed Caracelli, I. and Moran, P.J.S. and Hinoue, L. and Zukerman-Schpector, J. and Tiekink, E.R.T. (2010) Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate. Acta Crystallographica Section E: Structure Reports Online, 66 (2). O396-U2796. ISSN 1600-5368, |
| spellingShingle | QC Physics Caracelli, I. Moran, P.J.S. Hinoue, L. Zukerman-Schpector, J. Tiekink, E.R.T. Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate |
| title | Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate |
| title_full | Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate |
| title_fullStr | Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate |
| title_full_unstemmed | Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate |
| title_short | Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate |
| title_sort | ethyl e 2 methoxyimino 2 4 nitrobenzoyl acetate |
| topic | QC Physics |
| work_keys_str_mv | AT caracellii ethyle2methoxyimino24nitrobenzoylacetate AT moranpjs ethyle2methoxyimino24nitrobenzoylacetate AT hinouel ethyle2methoxyimino24nitrobenzoylacetate AT zukermanschpectorj ethyle2methoxyimino24nitrobenzoylacetate AT tiekinkert ethyle2methoxyimino24nitrobenzoylacetate |