Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II)
In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)(6)O(C4H8O)(H2O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, where...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720658575753216 |
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| author | Sadeghi, O. Amini, M.M. Ng, S.W. |
| author_facet | Sadeghi, O. Amini, M.M. Ng, S.W. |
| author_sort | Sadeghi, O. |
| collection | UM |
| description | In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)(6)O(C4H8O)(H2O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule. In the crystal, adjacent molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn-II atoms are disordered with respect to the Fe-III atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe. |
| first_indexed | 2024-03-06T05:38:28Z |
| format | Article |
| id | um.eprints-15277 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:28Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-152772019-01-31T04:51:33Z http://eprints.um.edu.my/15277/ Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II) Sadeghi, O. Amini, M.M. Ng, S.W. QC Physics In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)(6)O(C4H8O)(H2O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule. In the crystal, adjacent molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn-II atoms are disordered with respect to the Fe-III atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe. International Union of Crystallography 2010 Article PeerReviewed Sadeghi, O. and Amini, M.M. and Ng, S.W. (2010) Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II). Acta Crystallographica Section E: Structure Reports Online, 66 (1). M101-U1045. ISSN 1600-5368, |
| spellingShingle | QC Physics Sadeghi, O. Amini, M.M. Ng, S.W. Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II) |
| title | Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II) |
| title_full | Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II) |
| title_fullStr | Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II) |
| title_full_unstemmed | Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II) |
| title_short | Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II) |
| title_sort | diaquahexa mu 2 dichloroacetato mu 3 oxido tetrahydrofurandiiron iii m anganese ii |
| topic | QC Physics |
| work_keys_str_mv | AT sadeghio diaquahexamu2dichloroacetatomu3oxidotetrahydrofurandiironiiimanganeseii AT aminimm diaquahexamu2dichloroacetatomu3oxidotetrahydrofurandiironiiimanganeseii AT ngsw diaquahexamu2dichloroacetatomu3oxidotetrahydrofurandiironiiimanganeseii |