1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole
The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with 1,12-diazido-n-dodecane in the presence of catalysts leads to the formation of the title compound, C(38)H(46)N(8)O(2). The seven-membered diazepinyl ring adopts a boat conformation with the azidododecyltriazolylmethyl-bearing...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946879873810432 |
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| author | Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. |
| author_facet | Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. |
| author_sort | Jabli, H. |
| collection | UM |
| description | The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with 1,12-diazido-n-dodecane in the presence of catalysts leads to the formation of the title compound, C(38)H(46)N(8)O(2). The seven-membered diazepinyl ring adopts a boat conformation with the azidododecyltriazolylmethyl-bearing C atom as the prow and the fused-ring C atoms as the stern. The octyltriazolylmethyl substituent occupies an axial position. |
| first_indexed | 2024-03-06T05:38:30Z |
| format | Article |
| id | um.eprints-15294 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:30Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-152942019-01-31T04:25:13Z http://eprints.um.edu.my/15294/ 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. QC Physics The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with 1,12-diazido-n-dodecane in the presence of catalysts leads to the formation of the title compound, C(38)H(46)N(8)O(2). The seven-membered diazepinyl ring adopts a boat conformation with the azidododecyltriazolylmethyl-bearing C atom as the prow and the fused-ring C atoms as the stern. The octyltriazolylmethyl substituent occupies an axial position. International Union of Crystallography 2010 Article PeerReviewed Jabli, H. and Chahdi, F.O. and Saffon, N. and Essassi, E.M. and Ng, S.W. (2010) 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole. Acta Crystallographica Section E: Structure Reports Online, 66 (1). O232-U3096. ISSN 1600-5368, |
| spellingShingle | QC Physics Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole |
| title | 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole |
| title_full | 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole |
| title_fullStr | 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole |
| title_full_unstemmed | 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole |
| title_short | 1-(12-Azido-n-dodecyl)-4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1 H-1,5-benzodiazepin-3-yl)methyl]-1H-1,2,3-triazole |
| title_sort | 1 12 azido n dodecyl 4 1 5 dibenzyl 2 4 dioxo 2 3 4 5 tetrahydro 1 h 1 5 benzodiazepin 3 yl methyl 1h 1 2 3 triazole |
| topic | QC Physics |
| work_keys_str_mv | AT jablih 112azidondodecyl415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1h123triazole AT chahdifo 112azidondodecyl415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1h123triazole AT saffonn 112azidondodecyl415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1h123triazole AT essassiem 112azidondodecyl415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1h123triazole AT ngsw 112azidondodecyl415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1h123triazole |