4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole
The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4- dione with 1-azido-n-octane in the presence of catalysts leads to the formation of the title compound, C(34)H(39)N(5)O(2), which features a phenylene ring fused with a seven-membered diazepinyl ring. The latter ring adopts a boat confo...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946880074088448 |
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| author | Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. |
| author_facet | Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. |
| author_sort | Jabli, H. |
| collection | UM |
| description | The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4- dione with 1-azido-n-octane in the presence of catalysts leads to the formation of the title compound, C(34)H(39)N(5)O(2), which features a phenylene ring fused with a seven-membered diazepinyl ring. The latter ring adopts a boat conformation with the octyltriazolylmethyl-bearing C atom as the prow and the fused-ring C atoms as the stern. The octyltriazolylmethyl substituent occupies an axial position. |
| first_indexed | 2024-03-06T05:38:30Z |
| format | Article |
| id | um.eprints-15295 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:30Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-152952019-01-31T04:26:02Z http://eprints.um.edu.my/15295/ 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. QC Physics The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4- dione with 1-azido-n-octane in the presence of catalysts leads to the formation of the title compound, C(34)H(39)N(5)O(2), which features a phenylene ring fused with a seven-membered diazepinyl ring. The latter ring adopts a boat conformation with the octyltriazolylmethyl-bearing C atom as the prow and the fused-ring C atoms as the stern. The octyltriazolylmethyl substituent occupies an axial position. International Union of Crystallography 2010 Article PeerReviewed Jabli, H. and Chahdi, F.O. and Saffon, N. and Essassi, E.M. and Ng, S.W. (2010) 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole. Acta Crystallographica Section E: Structure Reports Online, 66 (1). O231-U3084. ISSN 1600-5368, |
| spellingShingle | QC Physics Jabli, H. Chahdi, F.O. Saffon, N. Essassi, E.M. Ng, S.W. 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole |
| title | 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole |
| title_full | 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole |
| title_fullStr | 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole |
| title_full_unstemmed | 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole |
| title_short | 4-[(1,5-Dibenzyl-2,4-dioxo-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-3-y l)methyl]-1-n-octyl-1H-1,2,3-triazole |
| title_sort | 4 1 5 dibenzyl 2 4 dioxo 2 3 4 5 tetrahydro 1h 1 5 benzodiazepin 3 y l methyl 1 n octyl 1h 1 2 3 triazole |
| topic | QC Physics |
| work_keys_str_mv | AT jablih 415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1noctyl1h123triazole AT chahdifo 415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1noctyl1h123triazole AT saffonn 415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1noctyl1h123triazole AT essassiem 415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1noctyl1h123triazole AT ngsw 415dibenzyl24dioxo2345tetrahydro1h15benzodiazepin3ylmethyl1noctyl1h123triazole |