1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate

In the title salt hydrate, C(22)H(30)N(2)O(6)(2+)center dot 2Cl(-)center dot CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O-H cent...

সম্পূর্ণ বিবরণ

গ্রন্থ-পঞ্জীর বিবরন
প্রধান লেখক: Johnson, S., Musie, G.T., Tiekink, E.R.T.
বিন্যাস: প্রবন্ধ
প্রকাশিত: International Union of Crystallography 2010
বিষয়গুলি:
বিবরন
সংক্ষিপ্ত:In the title salt hydrate, C(22)H(30)N(2)O(6)(2+)center dot 2Cl(-)center dot CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O-H center dot center dot center dot Cl(-), N(+)-H center dot center dot center dot Cl(-) and N(+)-H center dot center dot center dot O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C-H center dot center dot center dot O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C-H center dot center dot center dot pi contacts.