Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.
| Main Authors: | , , , |
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| Format: | Article |
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Royal Society of Chemistry
2010
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| _version_ | 1825720670052417536 |
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| author | Ibrahim, S. Woi, P.M. Alias, Y. Pickett, C.J. |
| author_facet | Ibrahim, S. Woi, P.M. Alias, Y. Pickett, C.J. |
| author_sort | Ibrahim, S. |
| collection | UM |
| description | We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix. |
| first_indexed | 2024-03-06T05:38:38Z |
| format | Article |
| id | um.eprints-15354 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:38Z |
| publishDate | 2010 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | um.eprints-153542017-07-03T08:57:31Z http://eprints.um.edu.my/15354/ Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix Ibrahim, S. Woi, P.M. Alias, Y. Pickett, C.J. R Medicine We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix. Royal Society of Chemistry 2010 Article PeerReviewed Ibrahim, S. and Woi, P.M. and Alias, Y. and Pickett, C.J. (2010) Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix. Chemical Communications, 46 (43). pp. 8189-8191. |
| spellingShingle | R Medicine Ibrahim, S. Woi, P.M. Alias, Y. Pickett, C.J. Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix |
| title | Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix |
| title_full | Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix |
| title_fullStr | Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix |
| title_full_unstemmed | Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix |
| title_short | Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix |
| title_sort | artificial hydrogenases assembly of an h cluster analogue within a functionalised poly pyrrole matrix |
| topic | R Medicine |
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