Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin a...
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Chinese Journal Structural Chemistry
2010
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| author | Ng, S.W. |
| author_facet | Ng, S.W. |
| author_sort | Ng, S.W. |
| collection | UM |
| description | Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%. |
| first_indexed | 2024-03-06T05:38:40Z |
| format | Article |
| id | um.eprints-15361 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:38:40Z |
| publishDate | 2010 |
| publisher | Chinese Journal Structural Chemistry |
| record_format | dspace |
| spelling | um.eprints-153612015-12-28T08:41:18Z http://eprints.um.edu.my/15361/ Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit Ng, S.W. Q Science (General) Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%. Chinese Journal Structural Chemistry 2010 Article PeerReviewed Ng, S.W. (2010) Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit. Chinese Journal of Structural Chemistry, 29 (10). pp. 1584-1586. |
| spellingShingle | Q Science (General) Ng, S.W. Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit |
| title | Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit |
| title_full | Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit |
| title_fullStr | Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit |
| title_full_unstemmed | Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit |
| title_short | Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit |
| title_sort | dimethyltin dichloride dibenzyl sulfoxide a compound crystallizing with seven molecules in the asymmetric unit |
| topic | Q Science (General) |
| work_keys_str_mv | AT ngsw dimethyltindichloridedibenzylsulfoxideacompoundcrystallizingwithsevenmoleculesintheasymmetricunit |