Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning

In this study, chitosan nanofibres were fabricated using electrospinning process. Initially, chitosan powders were further deacetylated with sodium hydroxide to deprotonate the polymer chains and decrease the molecular weight. Subsequently, the treated chitosan (5 wt-% in 90:10 acetic acid/water rat...

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Main Authors: Talebian, S., Afifi, A.M., Khanlou, H.M.
Format: Article
Published: Maney Publishing 2014
Subjects:
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author Talebian, S.
Afifi, A.M.
Khanlou, H.M.
author_facet Talebian, S.
Afifi, A.M.
Khanlou, H.M.
author_sort Talebian, S.
collection UM
description In this study, chitosan nanofibres were fabricated using electrospinning process. Initially, chitosan powders were further deacetylated with sodium hydroxide to deprotonate the polymer chains and decrease the molecular weight. Subsequently, the treated chitosan (5 wt-% in 90:10 acetic acid/water ratio) were mixed with poly vinyl alcohol (8 wt-% in water) at different ratios in order to facilitate the electrospinning through cross-links formation. Field-emission scanning electron microscopic images showed that 60:40 (chitosan/poly vinyl alcohol) ratio was the threshold for formation of beads (chitosan/poly vinyl alcohol >50:50 contains imperfections) and that increasing chitosan/poly vinyl alcohol ratio from 20:80 to 60:40 decreased the average diameter of fibres from 80 to 40 nm. Fourier transform infrared spectra proved the formation of chitosan/poly vinyl alcohol cross-linked nanofibres.
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institution Universiti Malaya
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publisher Maney Publishing
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spelling um.eprints-154772015-12-31T00:40:42Z http://eprints.um.edu.my/15477/ Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning Talebian, S. Afifi, A.M. Khanlou, H.M. Q Science (General) In this study, chitosan nanofibres were fabricated using electrospinning process. Initially, chitosan powders were further deacetylated with sodium hydroxide to deprotonate the polymer chains and decrease the molecular weight. Subsequently, the treated chitosan (5 wt-% in 90:10 acetic acid/water ratio) were mixed with poly vinyl alcohol (8 wt-% in water) at different ratios in order to facilitate the electrospinning through cross-links formation. Field-emission scanning electron microscopic images showed that 60:40 (chitosan/poly vinyl alcohol) ratio was the threshold for formation of beads (chitosan/poly vinyl alcohol >50:50 contains imperfections) and that increasing chitosan/poly vinyl alcohol ratio from 20:80 to 60:40 decreased the average diameter of fibres from 80 to 40 nm. Fourier transform infrared spectra proved the formation of chitosan/poly vinyl alcohol cross-linked nanofibres. Maney Publishing 2014 Article PeerReviewed Talebian, S. and Afifi, A.M. and Khanlou, H.M. (2014) Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning. Materials Research Innovations, 18 (S6). pp. 331-335.
spellingShingle Q Science (General)
Talebian, S.
Afifi, A.M.
Khanlou, H.M.
Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning
title Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning
title_full Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning
title_fullStr Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning
title_full_unstemmed Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning
title_short Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning
title_sort fabrication and characterisation of chitosan poly vinyl alcohol nanofibres via electrospinning
topic Q Science (General)
work_keys_str_mv AT talebians fabricationandcharacterisationofchitosanpolyvinylalcoholnanofibresviaelectrospinning
AT afifiam fabricationandcharacterisationofchitosanpolyvinylalcoholnanofibresviaelectrospinning
AT khanlouhm fabricationandcharacterisationofchitosanpolyvinylalcoholnanofibresviaelectrospinning