Polycaprolactone/starch composite: Fabrication, structure, properties, and applications

Interests in the use of biodegradable polymers as biomaterials have grown. Among the different polymeric composites currently available, the blend of starch and polycaprolactone (PCL) has received the most attention since the 1980s. Novamont is the first company that manufactured a PCL/starch (SPCL)...

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Main Authors: Ghavimi, S.A.A., Ebrahimzadeh, M.H., Solati-Hashjin, M., Abu Osman, Noor Azuan
Format: Article
Published: Wiley Black 2015
Subjects:
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author Ghavimi, S.A.A.
Ebrahimzadeh, M.H.
Solati-Hashjin, M.
Abu Osman, Noor Azuan
author_facet Ghavimi, S.A.A.
Ebrahimzadeh, M.H.
Solati-Hashjin, M.
Abu Osman, Noor Azuan
author_sort Ghavimi, S.A.A.
collection UM
description Interests in the use of biodegradable polymers as biomaterials have grown. Among the different polymeric composites currently available, the blend of starch and polycaprolactone (PCL) has received the most attention since the 1980s. Novamont is the first company that manufactured a PCL/starch (SPCL) composite under the trademark Mater-Bi (R). The properties of PCL (a synthetic, hydrophobic, flexible, expensive polymer with a low degradation rate) and starch (a natural, hydrophilic, stiff, abundant polymer with a high degradation rate) blends are interesting because of the composite components have completely different structures and characteristics. PCL can adjust humidity sensitivity of starch as a biomaterial; while starch can enhance the low biodegradation rate of PCL. Thus, by appropriate blending, SPCL can overcome important limitations of both PCL and starch components and promote controllable behavior in terms of mechanical properties and degradation which make it suitable for many biomedical applications. This article reviewed the different fabrication and modification methods of the SPCL composite; different properties such as structural, physical, and chemical as well as degradation behavior; and different applications as biomaterials. (c) 2014 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 103: 2482-2498, 2015.
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spelling um.eprints-157152019-02-07T07:41:18Z http://eprints.um.edu.my/15715/ Polycaprolactone/starch composite: Fabrication, structure, properties, and applications Ghavimi, S.A.A. Ebrahimzadeh, M.H. Solati-Hashjin, M. Abu Osman, Noor Azuan T Technology (General) TA Engineering (General). Civil engineering (General) Interests in the use of biodegradable polymers as biomaterials have grown. Among the different polymeric composites currently available, the blend of starch and polycaprolactone (PCL) has received the most attention since the 1980s. Novamont is the first company that manufactured a PCL/starch (SPCL) composite under the trademark Mater-Bi (R). The properties of PCL (a synthetic, hydrophobic, flexible, expensive polymer with a low degradation rate) and starch (a natural, hydrophilic, stiff, abundant polymer with a high degradation rate) blends are interesting because of the composite components have completely different structures and characteristics. PCL can adjust humidity sensitivity of starch as a biomaterial; while starch can enhance the low biodegradation rate of PCL. Thus, by appropriate blending, SPCL can overcome important limitations of both PCL and starch components and promote controllable behavior in terms of mechanical properties and degradation which make it suitable for many biomedical applications. This article reviewed the different fabrication and modification methods of the SPCL composite; different properties such as structural, physical, and chemical as well as degradation behavior; and different applications as biomaterials. (c) 2014 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 103: 2482-2498, 2015. Wiley Black 2015-07 Article PeerReviewed Ghavimi, S.A.A. and Ebrahimzadeh, M.H. and Solati-Hashjin, M. and Abu Osman, Noor Azuan (2015) Polycaprolactone/starch composite: Fabrication, structure, properties, and applications. Journal of Biomedical Materials Research Part A, 103 (7). pp. 2482-2498. ISSN 1549-3296, DOI https://doi.org/10.1002/jbm.a.35371 <https://doi.org/10.1002/jbm.a.35371>. http://www.ncbi.nlm.nih.gov/pubmed/25407786 10.1002/jbm.a.35371
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
Ghavimi, S.A.A.
Ebrahimzadeh, M.H.
Solati-Hashjin, M.
Abu Osman, Noor Azuan
Polycaprolactone/starch composite: Fabrication, structure, properties, and applications
title Polycaprolactone/starch composite: Fabrication, structure, properties, and applications
title_full Polycaprolactone/starch composite: Fabrication, structure, properties, and applications
title_fullStr Polycaprolactone/starch composite: Fabrication, structure, properties, and applications
title_full_unstemmed Polycaprolactone/starch composite: Fabrication, structure, properties, and applications
title_short Polycaprolactone/starch composite: Fabrication, structure, properties, and applications
title_sort polycaprolactone starch composite fabrication structure properties and applications
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
work_keys_str_mv AT ghavimisaa polycaprolactonestarchcompositefabricationstructurepropertiesandapplications
AT ebrahimzadehmh polycaprolactonestarchcompositefabricationstructurepropertiesandapplications
AT solatihashjinm polycaprolactonestarchcompositefabricationstructurepropertiesandapplications
AT abuosmannoorazuan polycaprolactonestarchcompositefabricationstructurepropertiesandapplications