Characterization of proton conducting carboxymethyf celiulose/chitosan dual-blend based biopolymer electrolytes

This article presents the discovery on biopolymer electrolytes comprising of ammonium nitrate, NH4N03 with dual-blend biopolymer materials, carboxymethyl cellulose/chitosan which were prepared via solution-casting technique. The biopolymer blend based electrolyte films were characterized by Fouri...

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Bibliographic Details
Main Authors: Mohd Saiful Asmal, R., Nor Sabirin, M., Mohd Ikmar Nizam, M.I.
Format: Conference or Workshop Item
Language:English
Published: 2014
Subjects:
Online Access:http://eprints.um.edu.my/15946/1/0001.pdf
Description
Summary:This article presents the discovery on biopolymer electrolytes comprising of ammonium nitrate, NH4N03 with dual-blend biopolymer materials, carboxymethyl cellulose/chitosan which were prepared via solution-casting technique. The biopolymer blend based electrolyte films were characterized by Fourier Transform Infrared spectroscopy to investigate the formation of the dualblend biopolymer based complexes. X-Ray Diffraction result showed that all dual-blend samples Werepredominantly amorphous. Electrochemical impedance spectroscopy was conducted to obtain their ionic conductivities. The highest conductivity at ambient temperature of 1.03 x 10-5 S cm-l was obtained for the electrolyte film containing 40 wt% of NH4N03. These results indicated that the dual-blend biopolymer based electrolyte has potential for application of electrochemical deVices.