Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution

Magnetized palm shell-waste based activated carbon (MPBAC) was prepared using a simple impregnation of magnetite into palm shell-waste based activated carbon (PBAC) and used for the removal of methylene blue (MB) from an aqueous solution. Based on the isotherm results, MPBAC with the smallest partic...

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Main Authors: Wong, K.T., Eu, N.C., Ibrahim, Shaliza, Kim, H., Yoon, Y., Jang, Min
Format: Article
Published: Elsevier 2016
Subjects:
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author Wong, K.T.
Eu, N.C.
Ibrahim, Shaliza
Kim, H.
Yoon, Y.
Jang, Min
author_facet Wong, K.T.
Eu, N.C.
Ibrahim, Shaliza
Kim, H.
Yoon, Y.
Jang, Min
author_sort Wong, K.T.
collection UM
description Magnetized palm shell-waste based activated carbon (MPBAC) was prepared using a simple impregnation of magnetite into palm shell-waste based activated carbon (PBAC) and used for the removal of methylene blue (MB) from an aqueous solution. Based on the isotherm results, MPBAC with the smallest particle size had the highest maximum adsorption capacity (Qmax = 163.3 mg g−1). Overall, the kinetic rates of MPBACs were slower than pristine PBACs due to the deposition of magnetite mostly on the outer surface. However, MB was electrostatically attracted towards the magnetite existing at the inner-pores and eventually adsorbed on the interface between the magnetite and the hydrophobic pore surface leading to high sorption density. The thermal regeneration indicated the removal capacities of MB by MPBAC were steady and higher than PBAC for repeated sorption. Through interpretation of thermogravimetric analysis and differential scanning calorimetry, the desorption energy of MB was lowered by the magnetite, leading to better regeneration ability for MPBAC.
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spelling um.eprints-174302019-03-13T04:45:10Z http://eprints.um.edu.my/17430/ Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution Wong, K.T. Eu, N.C. Ibrahim, Shaliza Kim, H. Yoon, Y. Jang, Min TA Engineering (General). Civil engineering (General) Magnetized palm shell-waste based activated carbon (MPBAC) was prepared using a simple impregnation of magnetite into palm shell-waste based activated carbon (PBAC) and used for the removal of methylene blue (MB) from an aqueous solution. Based on the isotherm results, MPBAC with the smallest particle size had the highest maximum adsorption capacity (Qmax = 163.3 mg g−1). Overall, the kinetic rates of MPBACs were slower than pristine PBACs due to the deposition of magnetite mostly on the outer surface. However, MB was electrostatically attracted towards the magnetite existing at the inner-pores and eventually adsorbed on the interface between the magnetite and the hydrophobic pore surface leading to high sorption density. The thermal regeneration indicated the removal capacities of MB by MPBAC were steady and higher than PBAC for repeated sorption. Through interpretation of thermogravimetric analysis and differential scanning calorimetry, the desorption energy of MB was lowered by the magnetite, leading to better regeneration ability for MPBAC. Elsevier 2016 Article PeerReviewed Wong, K.T. and Eu, N.C. and Ibrahim, Shaliza and Kim, H. and Yoon, Y. and Jang, Min (2016) Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution. Journal of Cleaner Production, 115. pp. 337-342. ISSN 0959-6526, DOI https://doi.org/10.1016/j.jclepro.2015.12.063 <https://doi.org/10.1016/j.jclepro.2015.12.063>. http://dx.doi.org/10.1016/j.jclepro.2015.12.063 doi:10.1016/j.jclepro.2015.12.063
spellingShingle TA Engineering (General). Civil engineering (General)
Wong, K.T.
Eu, N.C.
Ibrahim, Shaliza
Kim, H.
Yoon, Y.
Jang, Min
Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution
title Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution
title_full Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution
title_fullStr Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution
title_full_unstemmed Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution
title_short Recyclable magnetite-loaded palm shell-waste based activated carbon for the effective removal of methylene blue from aqueous solution
title_sort recyclable magnetite loaded palm shell waste based activated carbon for the effective removal of methylene blue from aqueous solution
topic TA Engineering (General). Civil engineering (General)
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