A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte

The objective of this work is to investigate the performance of chlorophyll sensitized solar cells (CSSCs) with gel electrolyte based on polyvinyl alcohol (PVA) with single iodide salt (potassium iodide (KI)) and double salt (KI and tetrapropylammonium iodide (TPAI)). Chlorophyll was extracted from...

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Main Authors: Hassan, H.C., Abidin, Zul Hazrin Zainal, Chowdhury, F.I., Arof, Abdul Kariem
Format: Article
Language:English
Published: Hindawi Publishing Corporation 2016
Subjects:
Online Access:http://eprints.um.edu.my/17515/1/HassanHC_%282016%29.pdf
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author Hassan, H.C.
Abidin, Zul Hazrin Zainal
Chowdhury, F.I.
Arof, Abdul Kariem
author_facet Hassan, H.C.
Abidin, Zul Hazrin Zainal
Chowdhury, F.I.
Arof, Abdul Kariem
author_sort Hassan, H.C.
collection UM
description The objective of this work is to investigate the performance of chlorophyll sensitized solar cells (CSSCs) with gel electrolyte based on polyvinyl alcohol (PVA) with single iodide salt (potassium iodide (KI)) and double salt (KI and tetrapropylammonium iodide (TPAI)). Chlorophyll was extracted from the bryophyte Hyophila involuta. The CSSC with electrolyte containing only KI salt produced a short circuit current density () of 4.59 mA cm−2, open circuit voltage () of 0.61 V, fill factor (FF) of 0.64, and efficiency () of 1.77%. However, the CSSC with double salt electrolyte exhibited of 5.96 mA cm−2, of 0.58 V, fill factor FF of 0.58, and of 2.00%. Since CSSC with double salt electrolyte showed better efficiency, other cells fabricated will use the double salt electrolyte. On addition of 0.7 M tetrabutyl pyridine (TBP) to the double salt electrolyte, the cell’s efficiency increased to 2.17%,  mA cm−2,  V, and FF = 0.73. With 5 mM chenodeoxycholic acid (CDCA) added to the chlorophyll, the light to electricity efficiency increased to 2.62% with of 8.44 mA cm−2, of 0.54 V, and FF of 0.58.
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spelling um.eprints-175152020-08-18T07:58:06Z http://eprints.um.edu.my/17515/ A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte Hassan, H.C. Abidin, Zul Hazrin Zainal Chowdhury, F.I. Arof, Abdul Kariem QC Physics The objective of this work is to investigate the performance of chlorophyll sensitized solar cells (CSSCs) with gel electrolyte based on polyvinyl alcohol (PVA) with single iodide salt (potassium iodide (KI)) and double salt (KI and tetrapropylammonium iodide (TPAI)). Chlorophyll was extracted from the bryophyte Hyophila involuta. The CSSC with electrolyte containing only KI salt produced a short circuit current density () of 4.59 mA cm−2, open circuit voltage () of 0.61 V, fill factor (FF) of 0.64, and efficiency () of 1.77%. However, the CSSC with double salt electrolyte exhibited of 5.96 mA cm−2, of 0.58 V, fill factor FF of 0.58, and of 2.00%. Since CSSC with double salt electrolyte showed better efficiency, other cells fabricated will use the double salt electrolyte. On addition of 0.7 M tetrabutyl pyridine (TBP) to the double salt electrolyte, the cell’s efficiency increased to 2.17%,  mA cm−2,  V, and FF = 0.73. With 5 mM chenodeoxycholic acid (CDCA) added to the chlorophyll, the light to electricity efficiency increased to 2.62% with of 8.44 mA cm−2, of 0.54 V, and FF of 0.58. Hindawi Publishing Corporation 2016 Article PeerReviewed application/pdf en http://eprints.um.edu.my/17515/1/HassanHC_%282016%29.pdf Hassan, H.C. and Abidin, Zul Hazrin Zainal and Chowdhury, F.I. and Arof, Abdul Kariem (2016) A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte. International Journal of Photoenergy, 2016. pp. 1-9. ISSN 1110-662X, DOI https://doi.org/10.1155/2016/3685210 <https://doi.org/10.1155/2016/3685210>. http://dx.doi.org/10.1155/2016/3685210 doi:10.1155/2016/3685210
spellingShingle QC Physics
Hassan, H.C.
Abidin, Zul Hazrin Zainal
Chowdhury, F.I.
Arof, Abdul Kariem
A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte
title A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte
title_full A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte
title_fullStr A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte
title_full_unstemmed A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte
title_short A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte
title_sort high efficiency chlorophyll sensitized solar cell with quasi solid pva based electrolyte
topic QC Physics
url http://eprints.um.edu.my/17515/1/HassanHC_%282016%29.pdf
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