Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin
The use of bovine skin gelatin in the synthesis of variety of nanostructures is a bio-friendly approach. In the current study, we investigated experimentally, for the first time, scalable process for production of homogeneous hexagonal zinc oxide nanoparticles (ZnO-NPs) not only with narrow size dis...
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| Format: | Article |
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Elsevier
2017
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| _version_ | 1796947178343628800 |
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| author | Alnarabiji, M.S. Yahya, N. Hamed, Y. Ardakani, S.E.M. Azizi, K. Klemeš, J.J. Abdullah, B. Tasfy, S.F.H. Hamid, Sharifah Bee Abd Nashed, O. |
| author_facet | Alnarabiji, M.S. Yahya, N. Hamed, Y. Ardakani, S.E.M. Azizi, K. Klemeš, J.J. Abdullah, B. Tasfy, S.F.H. Hamid, Sharifah Bee Abd Nashed, O. |
| author_sort | Alnarabiji, M.S. |
| collection | UM |
| description | The use of bovine skin gelatin in the synthesis of variety of nanostructures is a bio-friendly approach. In the current study, we investigated experimentally, for the first time, scalable process for production of homogeneous hexagonal zinc oxide nanoparticles (ZnO-NPs) not only with narrow size distribution and simple process but also cost effective and bio-friendly by green sol-gel method utilizing bovine skin gelatin (BSGB) matrix. Statistical analysis was done to evaluate the reliability of measuring the particle size using X-ray Diffraction analysis (XRD) and/or surface area (BET) instead of High Resolution Transmission Electron Microscope (HRTEM) and the following novel points are found. Impressively monodispersed ZnO-NPs with hexagonal structure were synthesized by adjusting the pH. All the samples exhibited hexagonal (wurtzite) crystal shape while the obtained morphology of the particles varies from hexagonal NPs to combination of hexagonal NPs and rod-like particles with reducing the pH from 6 to 2 due to the variation of bloom strength of the gelatin. Long chain gelatin contributed to suppressing the growth of nanoparticle and controlling the morphology. We discovered statistically that there was insignificant difference in measuring the particle size using XRD and HRTEM which can save time, energy, and cost at industrial aspect. |
| first_indexed | 2024-03-06T05:42:59Z |
| format | Article |
| id | um.eprints-17599 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:42:59Z |
| publishDate | 2017 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | um.eprints-175992018-10-19T04:06:17Z http://eprints.um.edu.my/17599/ Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin Alnarabiji, M.S. Yahya, N. Hamed, Y. Ardakani, S.E.M. Azizi, K. Klemeš, J.J. Abdullah, B. Tasfy, S.F.H. Hamid, Sharifah Bee Abd Nashed, O. QD Chemistry TP Chemical technology The use of bovine skin gelatin in the synthesis of variety of nanostructures is a bio-friendly approach. In the current study, we investigated experimentally, for the first time, scalable process for production of homogeneous hexagonal zinc oxide nanoparticles (ZnO-NPs) not only with narrow size distribution and simple process but also cost effective and bio-friendly by green sol-gel method utilizing bovine skin gelatin (BSGB) matrix. Statistical analysis was done to evaluate the reliability of measuring the particle size using X-ray Diffraction analysis (XRD) and/or surface area (BET) instead of High Resolution Transmission Electron Microscope (HRTEM) and the following novel points are found. Impressively monodispersed ZnO-NPs with hexagonal structure were synthesized by adjusting the pH. All the samples exhibited hexagonal (wurtzite) crystal shape while the obtained morphology of the particles varies from hexagonal NPs to combination of hexagonal NPs and rod-like particles with reducing the pH from 6 to 2 due to the variation of bloom strength of the gelatin. Long chain gelatin contributed to suppressing the growth of nanoparticle and controlling the morphology. We discovered statistically that there was insignificant difference in measuring the particle size using XRD and HRTEM which can save time, energy, and cost at industrial aspect. Elsevier 2017 Article PeerReviewed Alnarabiji, M.S. and Yahya, N. and Hamed, Y. and Ardakani, S.E.M. and Azizi, K. and Klemeš, J.J. and Abdullah, B. and Tasfy, S.F.H. and Hamid, Sharifah Bee Abd and Nashed, O. (2017) Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin. Journal of Cleaner Production, 162. pp. 186-194. ISSN 0959-6526, DOI https://doi.org/10.1016/j.jclepro.2017.06.010 <https://doi.org/10.1016/j.jclepro.2017.06.010>. http://dx.doi.org/10.1016/j.jclepro.2017.06.010 doi:10.1016/j.jclepro.2017.06.010 |
| spellingShingle | QD Chemistry TP Chemical technology Alnarabiji, M.S. Yahya, N. Hamed, Y. Ardakani, S.E.M. Azizi, K. Klemeš, J.J. Abdullah, B. Tasfy, S.F.H. Hamid, Sharifah Bee Abd Nashed, O. Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin |
| title | Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin |
| title_full | Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin |
| title_fullStr | Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin |
| title_full_unstemmed | Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin |
| title_short | Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin |
| title_sort | scalable bio friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin |
| topic | QD Chemistry TP Chemical technology |
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