Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template

Poly[2,7-(9,9-dioctylfluorene)-alt−4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole] (PFO-DBT) and o-xylenyl-C60-bisadduct (OXCBA) nanostructured composite has been fabricated via the hard porous alumina template-directed method. Spin-coating technique at the spin rate of 1000 rpm is used to assist the...

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Main Authors: Fakir, M.S., Supangat, Azzuliani, Sulaiman, Khaulah
Format: Article
Published: Wiley 2016
Subjects:
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author Fakir, M.S.
Supangat, Azzuliani
Sulaiman, Khaulah
author_facet Fakir, M.S.
Supangat, Azzuliani
Sulaiman, Khaulah
author_sort Fakir, M.S.
collection UM
description Poly[2,7-(9,9-dioctylfluorene)-alt−4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole] (PFO-DBT) and o-xylenyl-C60-bisadduct (OXCBA) nanostructured composite has been fabricated via the hard porous alumina template-directed method. Spin-coating technique at the spin rate of 1000 rpm is used to assist the infiltration of polymer solution into porous template. PFO-DBT nanotube is fabricated by replicating the porous alumina template before the formation of PFO-DBT:OXCBA nanostructured composite. Formation of nanostructured composite is completed once the infiltration of OXCBA solution into PFO-DBT nanotubes is achieved. Detailed results of morphological, structural, and optical properties of PFO-DBT nanostructures (nanorods and nanotubes) of different solution concentrations are reported. By tuning the optical properties of PFO-DBT nanostructures, the effect of solution concentration on the optical properties can be realized. The promising PFO-DBT nanotubes are chosen for the further fabrication of OXCBA:PFO-DBT nanostructured composite that acts as a core and shell, respectively. Although the nanostructured composite of PFO-DBT:OXCBA yield low light absorption intensity, the absorption spans the whole visible region and produce low optical energy gap.
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spelling um.eprints-176892019-03-18T02:08:44Z http://eprints.um.edu.my/17689/ Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template Fakir, M.S. Supangat, Azzuliani Sulaiman, Khaulah Q Science (General) QC Physics Poly[2,7-(9,9-dioctylfluorene)-alt−4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole] (PFO-DBT) and o-xylenyl-C60-bisadduct (OXCBA) nanostructured composite has been fabricated via the hard porous alumina template-directed method. Spin-coating technique at the spin rate of 1000 rpm is used to assist the infiltration of polymer solution into porous template. PFO-DBT nanotube is fabricated by replicating the porous alumina template before the formation of PFO-DBT:OXCBA nanostructured composite. Formation of nanostructured composite is completed once the infiltration of OXCBA solution into PFO-DBT nanotubes is achieved. Detailed results of morphological, structural, and optical properties of PFO-DBT nanostructures (nanorods and nanotubes) of different solution concentrations are reported. By tuning the optical properties of PFO-DBT nanostructures, the effect of solution concentration on the optical properties can be realized. The promising PFO-DBT nanotubes are chosen for the further fabrication of OXCBA:PFO-DBT nanostructured composite that acts as a core and shell, respectively. Although the nanostructured composite of PFO-DBT:OXCBA yield low light absorption intensity, the absorption spans the whole visible region and produce low optical energy gap. Wiley 2016 Article PeerReviewed Fakir, M.S. and Supangat, Azzuliani and Sulaiman, Khaulah (2016) Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template. Journal of Applied Polymer Science, 133 (47). ISSN 0021-8995, DOI https://doi.org/10.1002/app.44228 <https://doi.org/10.1002/app.44228>. http://dx.doi.org/10.1002/app.44228 doi:10.1002/app.44228
spellingShingle Q Science (General)
QC Physics
Fakir, M.S.
Supangat, Azzuliani
Sulaiman, Khaulah
Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template
title Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template
title_full Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template
title_fullStr Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template
title_full_unstemmed Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template
title_short Fabrication of PFO-DBT:OXCBA nanostructured composite via hard template
title_sort fabrication of pfo dbt oxcba nanostructured composite via hard template
topic Q Science (General)
QC Physics
work_keys_str_mv AT fakirms fabricationofpfodbtoxcbananostructuredcompositeviahardtemplate
AT supangatazzuliani fabricationofpfodbtoxcbananostructuredcompositeviahardtemplate
AT sulaimankhaulah fabricationofpfodbtoxcbananostructuredcompositeviahardtemplate