1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one
The piperidone ring in the title compound, C 20H 23NOS 2, has a half-chair distorted to a twisted-boat conformation [Q T = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.2...
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| Format: | Article |
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International Union of Crystallography
2011
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| _version_ | 1825718584345624576 |
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| author | Zukerman-Schpector, Julio Olivato, Paulo Roberto Cerqueira, Carlos R. Santos, Jean M.M. Ng, Seik Weng Tiekink, Edward R.T. |
| author_facet | Zukerman-Schpector, Julio Olivato, Paulo Roberto Cerqueira, Carlos R. Santos, Jean M.M. Ng, Seik Weng Tiekink, Edward R.T. |
| author_sort | Zukerman-Schpector, Julio |
| collection | UM |
| description | The piperidone ring in the title compound, C 20H 23NOS 2, has a half-chair distorted to a twisted-boat conformation [Q T = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.28 (5) and 46.41 (5) Å, respectively]. In the crystal, the presence of C-H⋯O and C-H⋯π interactions leads to the formation of supramolecular layers in the ab plane. |
| first_indexed | 2024-03-06T05:06:40Z |
| format | Article |
| id | um.eprints-1832 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:06:40Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-18322019-11-12T02:04:07Z http://eprints.um.edu.my/1832/ 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one Zukerman-Schpector, Julio Olivato, Paulo Roberto Cerqueira, Carlos R. Santos, Jean M.M. Ng, Seik Weng Tiekink, Edward R.T. Q Science (General) QD Chemistry The piperidone ring in the title compound, C 20H 23NOS 2, has a half-chair distorted to a twisted-boat conformation [Q T = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.28 (5) and 46.41 (5) Å, respectively]. In the crystal, the presence of C-H⋯O and C-H⋯π interactions leads to the formation of supramolecular layers in the ab plane. International Union of Crystallography 2011 Article PeerReviewed Zukerman-Schpector, Julio and Olivato, Paulo Roberto and Cerqueira, Carlos R. and Santos, Jean M.M. and Ng, Seik Weng and Tiekink, Edward R.T. (2011) 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one. Acta Crystallographica Section E: Structure Reports Online, 67 (10). o2759. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536811037111 <https://doi.org/10.1107/S1600536811037111>. https://doi.org/10.1107/S1600536811037111 doi:10.1107/S1600536811037111 |
| spellingShingle | Q Science (General) QD Chemistry Zukerman-Schpector, Julio Olivato, Paulo Roberto Cerqueira, Carlos R. Santos, Jean M.M. Ng, Seik Weng Tiekink, Edward R.T. 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one |
| title | 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one |
| title_full | 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one |
| title_fullStr | 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one |
| title_full_unstemmed | 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one |
| title_short | 1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one |
| title_sort | 1 methyl 3 3 bis 4 methyl phen yl sulfan yl piperidin 2 one |
| topic | Q Science (General) QD Chemistry |
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