Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid

The corrosion of lead in methanesulfonic acid solution in the presence of a MnO2 air cathode in a primary lead-air cell is investigated. The highest power density of the lead-air cell is 2.8 mW cm-2. X-ray photoelectron spectroscopy and powder X-ray diffraction results demonstrate the formation of l...

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Main Authors: Basirun, Wan Jefrey, Saeed, I.M., Ghadimi, H., Ladan, M., Mahmoudian, M.R., Ebadi, M., Abdulrauf, L.B., Endut, Z.
Format: Article
Published: Ecole Polytechnique de Montreal 2016
Subjects:
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author Basirun, Wan Jefrey
Saeed, I.M.
Ghadimi, H.
Ladan, M.
Mahmoudian, M.R.
Ebadi, M.
Abdulrauf, L.B.
Endut, Z.
author_facet Basirun, Wan Jefrey
Saeed, I.M.
Ghadimi, H.
Ladan, M.
Mahmoudian, M.R.
Ebadi, M.
Abdulrauf, L.B.
Endut, Z.
author_sort Basirun, Wan Jefrey
collection UM
description The corrosion of lead in methanesulfonic acid solution in the presence of a MnO2 air cathode in a primary lead-air cell is investigated. The highest power density of the lead-air cell is 2.8 mW cm-2. X-ray photoelectron spectroscopy and powder X-ray diffraction results demonstrate the formation of lead (II) oxide and lead (IV) dioxide on the air cathode after continuous discharge. Field emission scanning electron microscopy image shows that the surface coverage of lead (II) oxide and lead (IV) dioxide on the air cathode is only partial and will allow oxygen reduction.
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spelling um.eprints-184812019-01-31T07:27:10Z http://eprints.um.edu.my/18481/ Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid Basirun, Wan Jefrey Saeed, I.M. Ghadimi, H. Ladan, M. Mahmoudian, M.R. Ebadi, M. Abdulrauf, L.B. Endut, Z. Q Science (General) QD Chemistry The corrosion of lead in methanesulfonic acid solution in the presence of a MnO2 air cathode in a primary lead-air cell is investigated. The highest power density of the lead-air cell is 2.8 mW cm-2. X-ray photoelectron spectroscopy and powder X-ray diffraction results demonstrate the formation of lead (II) oxide and lead (IV) dioxide on the air cathode after continuous discharge. Field emission scanning electron microscopy image shows that the surface coverage of lead (II) oxide and lead (IV) dioxide on the air cathode is only partial and will allow oxygen reduction. Ecole Polytechnique de Montreal 2016 Article PeerReviewed Basirun, Wan Jefrey and Saeed, I.M. and Ghadimi, H. and Ladan, M. and Mahmoudian, M.R. and Ebadi, M. and Abdulrauf, L.B. and Endut, Z. (2016) Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid. Journal of New Materials for Electrochemical Systems, 19 (4). pp. 217-222. ISSN 1480-2422, DOI https://doi.org/10.14447/jnmes.v19i4.278 <https://doi.org/10.14447/jnmes.v19i4.278>. https://doi.org/10.14447/jnmes.v19i4.278 doi:10.14447/jnmes.v19i4.278
spellingShingle Q Science (General)
QD Chemistry
Basirun, Wan Jefrey
Saeed, I.M.
Ghadimi, H.
Ladan, M.
Mahmoudian, M.R.
Ebadi, M.
Abdulrauf, L.B.
Endut, Z.
Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid
title Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid
title_full Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid
title_fullStr Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid
title_full_unstemmed Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid
title_short Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid
title_sort lead corrosion and formation of lead oxides from a lead air cell in methanesulfonic acid
topic Q Science (General)
QD Chemistry
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