Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate
In the title salt, [Cu(NO3)(C7H6N 2)4]NO3, one nitrate anion is coordinated to the Cu II atom, which is also coordinated by the N atoms of four N-heterocycles. The geometry at the metal atom is a square pyramid in which the O atom of the anion occupies the apical position [Cu - O = 2.468 (5) and 2.5...
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| Format: | Article |
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International Union of Crystallography
2011
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| _version_ | 1796944772901896192 |
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| author | Zhou, Fu Lin Ng, Seik Weng |
| author_facet | Zhou, Fu Lin Ng, Seik Weng |
| author_sort | Zhou, Fu Lin |
| collection | UM |
| description | In the title salt, [Cu(NO3)(C7H6N 2)4]NO3, one nitrate anion is coordinated to the Cu II atom, which is also coordinated by the N atoms of four N-heterocycles. The geometry at the metal atom is a square pyramid in which the O atom of the anion occupies the apical position [Cu - O = 2.468 (5) and 2.590 (7) Å in the two independent formula units]. The cation lies on a twofold rotation axis; the coordinated nitrate anion is also disordered about this symmetry element. The lattice anion is also disordered about a twofold rotation axis. In the crystal, the cations are linked to the coordinated and free anions by N - H⋯O hydrogen bonds. |
| first_indexed | 2024-03-06T05:06:42Z |
| format | Article |
| id | um.eprints-1861 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:06:42Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-18612019-11-14T02:43:59Z http://eprints.um.edu.my/1861/ Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate Zhou, Fu Lin Ng, Seik Weng Q Science (General) QD Chemistry In the title salt, [Cu(NO3)(C7H6N 2)4]NO3, one nitrate anion is coordinated to the Cu II atom, which is also coordinated by the N atoms of four N-heterocycles. The geometry at the metal atom is a square pyramid in which the O atom of the anion occupies the apical position [Cu - O = 2.468 (5) and 2.590 (7) Å in the two independent formula units]. The cation lies on a twofold rotation axis; the coordinated nitrate anion is also disordered about this symmetry element. The lattice anion is also disordered about a twofold rotation axis. In the crystal, the cations are linked to the coordinated and free anions by N - H⋯O hydrogen bonds. International Union of Crystallography 2011 Article PeerReviewed Zhou, Fu Lin and Ng, Seik Weng (2011) Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate. Acta Crystallographica Section E: Structure Reports Online, 67 (6). m792. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536811018885 <https://doi.org/10.1107/S1600536811018885>. https://doi.org/10.1107/S1600536811018885 doi:10.1107/S1600536811018885 |
| spellingShingle | Q Science (General) QD Chemistry Zhou, Fu Lin Ng, Seik Weng Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate |
| title | Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate |
| title_full | Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate |
| title_fullStr | Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate |
| title_full_unstemmed | Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate |
| title_short | Tetra-kis(1H-benzimidazole-Nκ3)(nitrato-κO) copper(II) nitrate |
| title_sort | tetra kis 1h benzimidazole nκ3 nitrato κo copper ii nitrate |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT zhoufulin tetrakis1hbenzimidazolenk3nitratokocopperiinitrate AT ngseikweng tetrakis1hbenzimidazolenk3nitratokocopperiinitrate |