Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes
A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl⋯HNCS} were evaluated for the presence of intermolecular C-H⋯π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-,...
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De Gruyter
2016
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| author | Zukerman-Schpector, J. Yeo, C.I. Tiekink, E.R.T. |
| author_facet | Zukerman-Schpector, J. Yeo, C.I. Tiekink, E.R.T. |
| author_sort | Zukerman-Schpector, J. |
| collection | UM |
| description | A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl⋯HNCS} were evaluated for the presence of intermolecular C-H⋯π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-, two- and even three-dimensional architectures. Details of these interactions are described and a comparison to analogous interactions formed intramolecularly has been made. The C-H⋯π(quasi-chelate) interactions in these structures occur in one-third of structures where such contacts can potentially form. |
| first_indexed | 2024-03-06T05:45:56Z |
| format | Article |
| id | um.eprints-18651 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:45:56Z |
| publishDate | 2016 |
| publisher | De Gruyter |
| record_format | dspace |
| spelling | um.eprints-186512020-05-20T00:28:17Z http://eprints.um.edu.my/18651/ Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes Zukerman-Schpector, J. Yeo, C.I. Tiekink, E.R.T. Q Science (General) QD Chemistry A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl⋯HNCS} were evaluated for the presence of intermolecular C-H⋯π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-, two- and even three-dimensional architectures. Details of these interactions are described and a comparison to analogous interactions formed intramolecularly has been made. The C-H⋯π(quasi-chelate) interactions in these structures occur in one-third of structures where such contacts can potentially form. De Gruyter 2016 Article PeerReviewed Zukerman-Schpector, J. and Yeo, C.I. and Tiekink, E.R.T. (2016) Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes. Zeitschrift fur Kristallographie Crystalline Materials, 231 (1). pp. 55-64. ISSN 2194-4946, DOI https://doi.org/10.1515/zkri-2015-1868 <https://doi.org/10.1515/zkri-2015-1868>. https://doi.org/10.1515/zkri-2015-1868 doi:10.1515/zkri-2015-1868 |
| spellingShingle | Q Science (General) QD Chemistry Zukerman-Schpector, J. Yeo, C.I. Tiekink, E.R.T. Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes |
| title | Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes |
| title_full | Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes |
| title_fullStr | Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes |
| title_full_unstemmed | Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes |
| title_short | Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes |
| title_sort | supramolecular architectures sustained by arene c h⋯π quasi chelate ring interactions in the crystal structures of copper i complexes |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT zukermanschpectorj supramoleculararchitecturessustainedbyarenechpquasichelateringinteractionsinthecrystalstructuresofcoppericomplexes AT yeoci supramoleculararchitecturessustainedbyarenechpquasichelateringinteractionsinthecrystalstructuresofcoppericomplexes AT tiekinkert supramoleculararchitecturessustainedbyarenechpquasichelateringinteractionsinthecrystalstructuresofcoppericomplexes |