Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connect...
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Taylor & Francis
2017
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| author | Zhang, T. Li, R.F. Feng, X. Ng, S.W. Bai, RF. |
| author_facet | Zhang, T. Li, R.F. Feng, X. Ng, S.W. Bai, RF. |
| author_sort | Zhang, T. |
| collection | UM |
| description | A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connects Ho(III) atoms through one monodentate and one chelate carboxylate as well as one hydroxy group giving rise to a 2D wavelike polymer layer, which is extended by C–H O hydrogen bond and π π stacking interactions to give rise to a 3D supramolecular network. In addition, PXRD patterns and thermal gravimetric analysis (TGA) of sample 1 were investigated. |
| first_indexed | 2024-03-06T05:46:26Z |
| format | Article |
| id | um.eprints-18814 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:46:26Z |
| publishDate | 2017 |
| publisher | Taylor & Francis |
| record_format | dspace |
| spelling | um.eprints-188142018-06-06T06:41:52Z http://eprints.um.edu.my/18814/ Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline Zhang, T. Li, R.F. Feng, X. Ng, S.W. Bai, RF. Q Science (General) QD Chemistry A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connects Ho(III) atoms through one monodentate and one chelate carboxylate as well as one hydroxy group giving rise to a 2D wavelike polymer layer, which is extended by C–H O hydrogen bond and π π stacking interactions to give rise to a 3D supramolecular network. In addition, PXRD patterns and thermal gravimetric analysis (TGA) of sample 1 were investigated. Taylor & Francis 2017 Article PeerReviewed Zhang, T. and Li, R.F. and Feng, X. and Ng, S.W. and Bai, RF. (2017) Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline. Inorganic and Nano-Metal Chemistry, 47 (3). pp. 375-379. ISSN 2470-1556, DOI https://doi.org/10.1080/15533174.2016.1186065 <https://doi.org/10.1080/15533174.2016.1186065>. http://dx.doi.org/10.1080/15533174.2016.1186065 doi:10.1080/15533174.2016.1186065 |
| spellingShingle | Q Science (General) QD Chemistry Zhang, T. Li, R.F. Feng, X. Ng, S.W. Bai, RF. Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline |
| title | Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline |
| title_full | Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline |
| title_fullStr | Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline |
| title_full_unstemmed | Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline |
| title_short | Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline |
| title_sort | synthesis crystal structure and characterization of a lanthanide complex based on 4 4 oxypyridinium 1 yl phthalic acid and 1 10 phenanthroline |
| topic | Q Science (General) QD Chemistry |
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