Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis
The title compound, [Sn(CH3)2 (C5H8NOS2)2], has the SnIV atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating dithiocarbamate ligands so that the coordination geometry is skew-Trapezoidal bipyramidal. The most prominent feature of the molecular...
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| Format: | Article |
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International Union of Crystallography
2017
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| _version_ | 1825721183139528704 |
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| author | Zaldi, N. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. |
| author_facet | Zaldi, N. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. |
| author_sort | Zaldi, N. |
| collection | UM |
| description | The title compound, [Sn(CH3)2 (C5H8NOS2)2], has the SnIV atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating dithiocarbamate ligands so that the coordination geometry is skew-Trapezoidal bipyramidal. The most prominent feature of the molecular packing are secondary Sn⋯S interactions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methylene-C-H⋯S and methyl-C-H⋯O(morpholino) interactions. The Sn⋯S interactions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other intermolecular contacts. |
| first_indexed | 2024-03-06T05:46:30Z |
| format | Article |
| id | um.eprints-18836 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:46:30Z |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-188362019-01-31T08:37:38Z http://eprints.um.edu.my/18836/ Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis Zaldi, N. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. Q Science (General) QD Chemistry The title compound, [Sn(CH3)2 (C5H8NOS2)2], has the SnIV atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating dithiocarbamate ligands so that the coordination geometry is skew-Trapezoidal bipyramidal. The most prominent feature of the molecular packing are secondary Sn⋯S interactions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methylene-C-H⋯S and methyl-C-H⋯O(morpholino) interactions. The Sn⋯S interactions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other intermolecular contacts. International Union of Crystallography 2017 Article PeerReviewed Zaldi, N. and Hussen, R.S.D. and Lee, S.M. and Halcovitch, N.R. and Jotani, M.M. and Tiekink, E.R.T. (2017) Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Crystallographic Communications, 73 (6). pp. 842-848. ISSN 2056-9890, DOI https://doi.org/10.1107/S2056989017006855 <https://doi.org/10.1107/S2056989017006855>. http://dx.doi.org/10.1107/S2056989017006855 doi:10.1107/S2056989017006855 |
| spellingShingle | Q Science (General) QD Chemistry Zaldi, N. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis |
| title | Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_full | Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_fullStr | Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_short | Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_sort | secondary bonding in dimethylbis morpholine 4 carbodithioato κ2 s s tin iv crystal structure and hirshfeld surface analysis |
| topic | Q Science (General) QD Chemistry |
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