Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings
A study has been presented on the effects of intrinsic mechanical parameters, such as surface stress, surface elastic modulus, surface porosity, permeability and grain size on the corrosion failure of nanocomposite coatings. A set of mechano-electrochemical equations was developed by combining the p...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI
2017
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| Online Access: | http://eprints.um.edu.my/19079/1/Analyzing_and_Modelling_the_Corrosion_Behavior.pdf |
| _version_ | 1825721229567328256 |
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| author | Nazir, M.H. Khan, Z.A. Saeed, A. Bakolas, V. Braun, W. Bajwa, R. Rafique, S. |
| author_facet | Nazir, M.H. Khan, Z.A. Saeed, A. Bakolas, V. Braun, W. Bajwa, R. Rafique, S. |
| author_sort | Nazir, M.H. |
| collection | UM |
| description | A study has been presented on the effects of intrinsic mechanical parameters, such as surface stress, surface elastic modulus, surface porosity, permeability and grain size on the corrosion failure of nanocomposite coatings. A set of mechano-electrochemical equations was developed by combining the popular Butler-Volmer and Duhem expressions to analyze the direct influence of mechanical parameters on the electrochemical reactions in nanocomposite coatings. Nanocomposite coatings of Ni with Al2O3, SiC, ZrO2 and Graphene nanoparticles were studied as examples. The predictions showed that the corrosion rate of the nanocoatings increased with increasing grain size due to increase in surface stress, surface porosity and permeability of nanocoatings. A detailed experimental study was performed in which the nanocomposite coatings were subjected to an accelerated corrosion testing. The experimental results helped to develop and validate the equations by qualitative comparison between the experimental and predicted results showing good agreement between the two. |
| first_indexed | 2024-03-06T05:47:12Z |
| format | Article |
| id | um.eprints-19079 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:47:12Z |
| publishDate | 2017 |
| publisher | MDPI |
| record_format | dspace |
| spelling | um.eprints-190792018-09-04T03:48:18Z http://eprints.um.edu.my/19079/ Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings Nazir, M.H. Khan, Z.A. Saeed, A. Bakolas, V. Braun, W. Bajwa, R. Rafique, S. Q Science (General) QC Physics A study has been presented on the effects of intrinsic mechanical parameters, such as surface stress, surface elastic modulus, surface porosity, permeability and grain size on the corrosion failure of nanocomposite coatings. A set of mechano-electrochemical equations was developed by combining the popular Butler-Volmer and Duhem expressions to analyze the direct influence of mechanical parameters on the electrochemical reactions in nanocomposite coatings. Nanocomposite coatings of Ni with Al2O3, SiC, ZrO2 and Graphene nanoparticles were studied as examples. The predictions showed that the corrosion rate of the nanocoatings increased with increasing grain size due to increase in surface stress, surface porosity and permeability of nanocoatings. A detailed experimental study was performed in which the nanocomposite coatings were subjected to an accelerated corrosion testing. The experimental results helped to develop and validate the equations by qualitative comparison between the experimental and predicted results showing good agreement between the two. MDPI 2017 Article PeerReviewed application/pdf en http://eprints.um.edu.my/19079/1/Analyzing_and_Modelling_the_Corrosion_Behavior.pdf Nazir, M.H. and Khan, Z.A. and Saeed, A. and Bakolas, V. and Braun, W. and Bajwa, R. and Rafique, S. (2017) Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings. Materials, 10 (11). p. 1225. ISSN 1996-1944, DOI https://doi.org/10.3390/ma10111225 <https://doi.org/10.3390/ma10111225>. http://dx.doi.org/10.3390/ma10111225 doi:10.3390/ma10111225 |
| spellingShingle | Q Science (General) QC Physics Nazir, M.H. Khan, Z.A. Saeed, A. Bakolas, V. Braun, W. Bajwa, R. Rafique, S. Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings |
| title | Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings |
| title_full | Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings |
| title_fullStr | Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings |
| title_full_unstemmed | Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings |
| title_short | Analyzing and Modelling the Corrosion Behavior of Ni/Al2O3, Ni/SiC, Ni/ZrO2 and Ni/Graphene Nanocomposite Coatings |
| title_sort | analyzing and modelling the corrosion behavior of ni al2o3 ni sic ni zro2 and ni graphene nanocomposite coatings |
| topic | Q Science (General) QC Physics |
| url | http://eprints.um.edu.my/19079/1/Analyzing_and_Modelling_the_Corrosion_Behavior.pdf |
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