trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis
The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C - H⋯F, C - H⋯Cl and C - H⋯π i...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2017
|
| Subjects: |
| _version_ | 1825721231730540544 |
|---|---|
| author | Amin, N.A.M. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. |
| author_facet | Amin, N.A.M. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. |
| author_sort | Amin, N.A.M. |
| collection | UM |
| description | The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C - H⋯F, C - H⋯Cl and C - H⋯π interactions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface. |
| first_indexed | 2024-03-06T05:47:15Z |
| format | Article |
| id | um.eprints-19090 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:47:15Z |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-190902018-09-04T05:34:19Z http://eprints.um.edu.my/19090/ trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis Amin, N.A.M. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. Q Science (General) QD Chemistry The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C - H⋯F, C - H⋯Cl and C - H⋯π interactions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface. International Union of Crystallography 2017 Article PeerReviewed Amin, N.A.M. and Hussen, R.S.D. and Lee, S.M. and Halcovitch, N.R. and Jotani, M.M. and Tiekink, E.R.T. (2017) trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Crystallographic Communications, 73 (5). pp. 667-672. ISSN 2056-9890, DOI https://doi.org/10.1107/S2056989017005072 <https://doi.org/10.1107/S2056989017005072>. http://dx.doi.org/10.1107/S2056989017005072 doi:10.1107/S2056989017005072 |
| spellingShingle | Q Science (General) QD Chemistry Amin, N.A.M. Hussen, R.S.D. Lee, S.M. Halcovitch, N.R. Jotani, M.M. Tiekink, E.R.T. trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis |
| title | trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_full | trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_fullStr | trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_short | trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis |
| title_sort | trans dichloridobis dimethyl sulfoxide κo bis 4 fluorobenzyl κc1 tin iv crystal structure and hirshfeld surface analysis |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT aminnam transdichloridobisdimethylsulfoxidekobis4fluorobenzylkc1tinivcrystalstructureandhirshfeldsurfaceanalysis AT hussenrsd transdichloridobisdimethylsulfoxidekobis4fluorobenzylkc1tinivcrystalstructureandhirshfeldsurfaceanalysis AT leesm transdichloridobisdimethylsulfoxidekobis4fluorobenzylkc1tinivcrystalstructureandhirshfeldsurfaceanalysis AT halcovitchnr transdichloridobisdimethylsulfoxidekobis4fluorobenzylkc1tinivcrystalstructureandhirshfeldsurfaceanalysis AT jotanimm transdichloridobisdimethylsulfoxidekobis4fluorobenzylkc1tinivcrystalstructureandhirshfeldsurfaceanalysis AT tiekinkert transdichloridobisdimethylsulfoxidekobis4fluorobenzylkc1tinivcrystalstructureandhirshfeldsurfaceanalysis |