PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector

We present a ternary blend-based bulk heterojunction ITO/PEDOT:PSS/PFO-DBT: MEH-PPV:PC71BM/LiF/Al photodetector. Enhanced optical absorption range of the active film has been achieved by blending two donor components viz. poly[2,7-(9,9-di-octylfluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiaz...

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Main Authors: Zafar, Q., Ahmad, Z., Sulaiman, K.
Format: Article
Published: MDPI 2015
Subjects:
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author Zafar, Q.
Ahmad, Z.
Sulaiman, K.
author_facet Zafar, Q.
Ahmad, Z.
Sulaiman, K.
author_sort Zafar, Q.
collection UM
description We present a ternary blend-based bulk heterojunction ITO/PEDOT:PSS/PFO-DBT: MEH-PPV:PC71BM/LiF/Al photodetector. Enhanced optical absorption range of the active film has been achieved by blending two donor components viz. poly[2,7-(9,9-di-octylfluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole] (PFO-DBT) and poly(2-methoxy-5(2'-ethylhexyloxy) phenylenevinylene (MEH-PPV) along with an acceptor component, i.e., (6,6)-phenyl-C71 hexnoic acid methyl ester. The dependency of the generation rate of free charge carriers in the organic photodetector (OPD) on varied incident optical power density was investigated as a function of different reverse biasing voltages. The photocurrent showed significant enhancement as the intensity of light impinging on active area of OPD is increased. The ratio of Ilight to Idark of fabricated device at -3 V was ∼3.5 × 104. The dynamic behaviour of the OPD under on/off switching irradiation revealed that sensor exhibits quick response and recovery time of <800 ms and 500 ms, respectively. Besides reliability and repeatability in the photoresponse characteristics, the cost-effective and eco-friendly fabrication is the added benefit of the fabricated OPD.
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spelling um.eprints-193182018-09-20T04:33:22Z http://eprints.um.edu.my/19318/ PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector Zafar, Q. Ahmad, Z. Sulaiman, K. Q Science (General) QC Physics We present a ternary blend-based bulk heterojunction ITO/PEDOT:PSS/PFO-DBT: MEH-PPV:PC71BM/LiF/Al photodetector. Enhanced optical absorption range of the active film has been achieved by blending two donor components viz. poly[2,7-(9,9-di-octylfluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole] (PFO-DBT) and poly(2-methoxy-5(2'-ethylhexyloxy) phenylenevinylene (MEH-PPV) along with an acceptor component, i.e., (6,6)-phenyl-C71 hexnoic acid methyl ester. The dependency of the generation rate of free charge carriers in the organic photodetector (OPD) on varied incident optical power density was investigated as a function of different reverse biasing voltages. The photocurrent showed significant enhancement as the intensity of light impinging on active area of OPD is increased. The ratio of Ilight to Idark of fabricated device at -3 V was ∼3.5 × 104. The dynamic behaviour of the OPD under on/off switching irradiation revealed that sensor exhibits quick response and recovery time of <800 ms and 500 ms, respectively. Besides reliability and repeatability in the photoresponse characteristics, the cost-effective and eco-friendly fabrication is the added benefit of the fabricated OPD. MDPI 2015 Article PeerReviewed Zafar, Q. and Ahmad, Z. and Sulaiman, K. (2015) PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector. Sensors, 15 (1). pp. 965-978. ISSN 1424-8220, DOI https://doi.org/10.3390/s150100965 <https://doi.org/10.3390/s150100965>. http://dx.doi.org/10.3390/s150100965 doi:10.3390/s150100965
spellingShingle Q Science (General)
QC Physics
Zafar, Q.
Ahmad, Z.
Sulaiman, K.
PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector
title PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector
title_full PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector
title_fullStr PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector
title_full_unstemmed PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector
title_short PFO-DBT:MEH-PPV:PC71BM Ternary Blend Assisted Platform as a Photodetector
title_sort pfo dbt meh ppv pc71bm ternary blend assisted platform as a photodetector
topic Q Science (General)
QC Physics
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AT ahmadz pfodbtmehppvpc71bmternaryblendassistedplatformasaphotodetector
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