A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands
In the linear coordination polymer catena-poly[[[aqua(1,10-phenanthroline-κ2 N,N')copper(II)]-μ-pyridine-2,6-dicarboxylato-κ4 O2:O2',N,O6-[(nitrato-κ2 O,O')bismuth(III)]-μ-pyridine-2,6-dicarboxylato-κ4 O2,N,O6:O6'] dihydrate], {[BiIIICuII(C7H3NO4)2(NO3)(C12H8N2)(H2O)]·2H2O} n , t...
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| Format: | Article |
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International Union of Crystallography
2015
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| _version_ | 1825721279698698240 |
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| author | Yue, Z.L. Feng, Y.Q. Ng, S.W. |
| author_facet | Yue, Z.L. Feng, Y.Q. Ng, S.W. |
| author_sort | Yue, Z.L. |
| collection | UM |
| description | In the linear coordination polymer catena-poly[[[aqua(1,10-phenanthroline-κ2 N,N')copper(II)]-μ-pyridine-2,6-dicarboxylato-κ4 O2:O2',N,O6-[(nitrato-κ2 O,O')bismuth(III)]-μ-pyridine-2,6-dicarboxylato-κ4 O2,N,O6:O6'] dihydrate], {[BiIIICuII(C7H3NO4)2(NO3)(C12H8N2)(H2O)]·2H2O} n , the BiIII cation is O,N,O'-chelated by the two pyridine-2,6-dicarboxylate ligands and O,O'-chelated by the nitrate anion, the nine coordinating atoms conferring a tricapped trigonal prismatic environment on the metal centre. Each pyridine-2,6-dicarboxylate ligand uses one of its carboxylate O atoms to bind to an aqua(1,10-phenanthroline)copper(II) unit, the Cu-O dative bonds giving rise to the formation of a ribbon motif. The CuII cation exhibits a square-pyramidal geometry. The ribbon motif propagates along the shortest axis of the triclinic unit cell and the solvent water molecules are hydrogen bonded to the same ribbon. |
| first_indexed | 2024-03-06T05:47:59Z |
| format | Article |
| id | um.eprints-19335 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:47:59Z |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-193352018-09-20T06:28:33Z http://eprints.um.edu.my/19335/ A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands Yue, Z.L. Feng, Y.Q. Ng, S.W. Q Science (General) QD Chemistry In the linear coordination polymer catena-poly[[[aqua(1,10-phenanthroline-κ2 N,N')copper(II)]-μ-pyridine-2,6-dicarboxylato-κ4 O2:O2',N,O6-[(nitrato-κ2 O,O')bismuth(III)]-μ-pyridine-2,6-dicarboxylato-κ4 O2,N,O6:O6'] dihydrate], {[BiIIICuII(C7H3NO4)2(NO3)(C12H8N2)(H2O)]·2H2O} n , the BiIII cation is O,N,O'-chelated by the two pyridine-2,6-dicarboxylate ligands and O,O'-chelated by the nitrate anion, the nine coordinating atoms conferring a tricapped trigonal prismatic environment on the metal centre. Each pyridine-2,6-dicarboxylate ligand uses one of its carboxylate O atoms to bind to an aqua(1,10-phenanthroline)copper(II) unit, the Cu-O dative bonds giving rise to the formation of a ribbon motif. The CuII cation exhibits a square-pyramidal geometry. The ribbon motif propagates along the shortest axis of the triclinic unit cell and the solvent water molecules are hydrogen bonded to the same ribbon. International Union of Crystallography 2015 Article PeerReviewed Yue, Z.L. and Feng, Y.Q. and Ng, S.W. (2015) A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands. Acta Crystallographica Section C: Structural Chemistry, 71 (2). pp. 100-102. ISSN 2053-2296, DOI https://doi.org/10.1107/S2053229614028125 <https://doi.org/10.1107/S2053229614028125>. https://doi.org/10.1107/S2053229614028125 doi:10.1107/S2053229614028125 |
| spellingShingle | Q Science (General) QD Chemistry Yue, Z.L. Feng, Y.Q. Ng, S.W. A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands |
| title | A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands |
| title_full | A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands |
| title_fullStr | A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands |
| title_full_unstemmed | A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands |
| title_short | A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands |
| title_sort | linear heterometallic bismuth copper coordination polymer containing two types of organic ligands |
| topic | Q Science (General) QD Chemistry |
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