Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor
A new monoterpene indole alkaloid characterized by an unprecedented pentacyclic cage skeleton, arboridinine (1), was isolated from a Malaysian Kopsia species. The structure and absolute configuration of the alkaloid were determined based on NMR, MS, and X-ray diffraction analysis. A possible biogene...
| Principais autores: | , , , , , |
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| Formato: | Artigo |
| Publicado em: |
American Chemical Society
2015
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| Assuntos: |
| _version_ | 1825721300499300352 |
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| author | Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S. |
| author_facet | Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S. |
| author_sort | Wong, S.P. |
| collection | UM |
| description | A new monoterpene indole alkaloid characterized by an unprecedented pentacyclic cage skeleton, arboridinine (1), was isolated from a Malaysian Kopsia species. The structure and absolute configuration of the alkaloid were determined based on NMR, MS, and X-ray diffraction analysis. A possible biogenetic pathway from a pericine precursor is presented. |
| first_indexed | 2024-03-06T05:48:18Z |
| format | Article |
| id | um.eprints-19443 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:48:18Z |
| publishDate | 2015 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | um.eprints-194432018-09-28T02:17:44Z http://eprints.um.edu.my/19443/ Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S. Q Science (General) QA75 Electronic computers. Computer science QD Chemistry R Medicine TA Engineering (General). Civil engineering (General) A new monoterpene indole alkaloid characterized by an unprecedented pentacyclic cage skeleton, arboridinine (1), was isolated from a Malaysian Kopsia species. The structure and absolute configuration of the alkaloid were determined based on NMR, MS, and X-ray diffraction analysis. A possible biogenetic pathway from a pericine precursor is presented. American Chemical Society 2015 Article PeerReviewed Wong, S.P. and Gan, C.Y. and Lim, K.H. and Ting, K.N. and Low, Y.Y. and Kam, T.S. (2015) Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor. Organic Letters, 17 (14). pp. 3628-3631. ISSN 1523-7060, DOI https://doi.org/10.1021/acs.orglett.5b01757 <https://doi.org/10.1021/acs.orglett.5b01757>. http://dx.doi.org/10.1021/acs.orglett.5b01757 doi:10.1021/acs.orglett.5b01757 |
| spellingShingle | Q Science (General) QA75 Electronic computers. Computer science QD Chemistry R Medicine TA Engineering (General). Civil engineering (General) Wong, S.P. Gan, C.Y. Lim, K.H. Ting, K.N. Low, Y.Y. Kam, T.S. Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor |
| title | Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor |
| title_full | Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor |
| title_fullStr | Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor |
| title_full_unstemmed | Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor |
| title_short | Arboridinine, a Pentacyclic Indole Alkaloid with a New Cage Carbon–Nitrogen Skeleton Derived from a Pericine Precursor |
| title_sort | arboridinine a pentacyclic indole alkaloid with a new cage carbon nitrogen skeleton derived from a pericine precursor |
| topic | Q Science (General) QA75 Electronic computers. Computer science QD Chemistry R Medicine TA Engineering (General). Civil engineering (General) |
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