Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole
Three new metal coordination polymers constructed from adipic acid and 2-(pyridin-3-yl)-(1H)-benzimidazole ligands, [M(ADP)(3PBI)2(H2O)2]·2H2O (M = Ni and Co for 1 and 2, respectively) and [Cd(ADP)(3PBI)(H2O)] (3) [ADP = adipic acid dianion; 3PBI = 2-(pyridin-3-yl)-(1H)-benzimidazole], have been syn...
| मुख्य लेखकों: | , , , , , |
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| स्वरूप: | लेख |
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Taylor & Francis
2015
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| विषय: |
| _version_ | 1825721307091697664 |
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| author | Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W. |
| author_facet | Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W. |
| author_sort | Wang, C.C. |
| collection | UM |
| description | Three new metal coordination polymers constructed from adipic acid and 2-(pyridin-3-yl)-(1H)-benzimidazole ligands, [M(ADP)(3PBI)2(H2O)2]·2H2O (M = Ni and Co for 1 and 2, respectively) and [Cd(ADP)(3PBI)(H2O)] (3) [ADP = adipic acid dianion; 3PBI = 2-(pyridin-3-yl)-(1H)-benzimidazole], have been synthesized by hydrothermal reactions and were characterized by X-ray single-crystal diffraction, elemental analyses, IR, powder X-ray diffraction, and thermogravimetry. Complexes 1 and 2 are isostructural. Both form a 1-D linear chain structure, which is further assembled into a 3-D supramolecular framework by ππ stacking and hydrogen bonding interactions. Complex 3 possesses a binuclear unit and displays a 2-D layer which is further extended to a 3-D supramolecular architecture via hydrogen bonding and other weak packing interactions. The luminescent properties of 3 were investigated in the solid state at room temperature. |
| first_indexed | 2024-03-06T05:48:24Z |
| format | Article |
| id | um.eprints-19477 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:48:24Z |
| publishDate | 2015 |
| publisher | Taylor & Francis |
| record_format | dspace |
| spelling | um.eprints-194772018-09-28T08:32:56Z http://eprints.um.edu.my/19477/ Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W. QD Chemistry TP Chemical technology Three new metal coordination polymers constructed from adipic acid and 2-(pyridin-3-yl)-(1H)-benzimidazole ligands, [M(ADP)(3PBI)2(H2O)2]·2H2O (M = Ni and Co for 1 and 2, respectively) and [Cd(ADP)(3PBI)(H2O)] (3) [ADP = adipic acid dianion; 3PBI = 2-(pyridin-3-yl)-(1H)-benzimidazole], have been synthesized by hydrothermal reactions and were characterized by X-ray single-crystal diffraction, elemental analyses, IR, powder X-ray diffraction, and thermogravimetry. Complexes 1 and 2 are isostructural. Both form a 1-D linear chain structure, which is further assembled into a 3-D supramolecular framework by ππ stacking and hydrogen bonding interactions. Complex 3 possesses a binuclear unit and displays a 2-D layer which is further extended to a 3-D supramolecular architecture via hydrogen bonding and other weak packing interactions. The luminescent properties of 3 were investigated in the solid state at room temperature. Taylor & Francis 2015 Article PeerReviewed Wang, C.C. and Wang, J.H. and Tang, G.M. and Wang, Y.T. and Cui, Y.Z. and Ng, S.W. (2015) Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole. Journal of Coordination Chemistry, 68 (21). pp. 3918-3931. ISSN 0095-8972, DOI https://doi.org/10.1080/00958972.2015.1084418 <https://doi.org/10.1080/00958972.2015.1084418>. http://dx.doi.org/10.1080/00958972.2015.1084418 doi:10.1080/00958972.2015.1084418 |
| spellingShingle | QD Chemistry TP Chemical technology Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W. Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole |
| title | Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole |
| title_full | Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole |
| title_fullStr | Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole |
| title_full_unstemmed | Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole |
| title_short | Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole |
| title_sort | syntheses crystal structures and luminescent properties of three metal coordination polymers based on adipic acid and 2 pyridine 3 yl 1h benzimidazole |
| topic | QD Chemistry TP Chemical technology |
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