Production optimization and tribological characteristics of cottonseed oil methyl ester

This paper presented experimental results to evaluate the optimization of production parameters through response surface methodology. These parameters significantly affected the yield of cottonseed oil methyl ester (COME). The input variables for the production of methyl ester from cottonseed oil we...

Ausführliche Beschreibung

Bibliographische Detailangaben
Hauptverfasser: Jamshaid, Muhammad, Masjuki, Haji Hassan, Kalam, Md. Abul, Zulkifli, Nurin Wahidah Mohd, Arslan, Ahmed, Alwi, Azham, Khuong, Leang So, Alabdulkarem, Abdullah, Syahir, A.Z.
Format: Artikel
Veröffentlicht: Elsevier 2019
Schlagworte:
_version_ 1825721421313081344
author Jamshaid, Muhammad
Masjuki, Haji Hassan
Kalam, Md. Abul
Zulkifli, Nurin Wahidah Mohd
Arslan, Ahmed
Alwi, Azham
Khuong, Leang So
Alabdulkarem, Abdullah
Syahir, A.Z.
author_facet Jamshaid, Muhammad
Masjuki, Haji Hassan
Kalam, Md. Abul
Zulkifli, Nurin Wahidah Mohd
Arslan, Ahmed
Alwi, Azham
Khuong, Leang So
Alabdulkarem, Abdullah
Syahir, A.Z.
author_sort Jamshaid, Muhammad
collection UM
description This paper presented experimental results to evaluate the optimization of production parameters through response surface methodology. These parameters significantly affected the yield of cottonseed oil methyl ester (COME). The input variables for the production of methyl ester from cottonseed oil were methanol/oil molar ratio, concentration of catalyst, temperature, and stirring speed. The response or output variable was the yield of methyl ester. The fatty acid methyl ester composition of COME (biodiesel) was obtained using a gas chromatography (GC) analyzer. BS EN 14103:2011 was the standard used to analyze the fatty acid methyl ester. The derived mathematical model was statistically accurate to predict the optimum value of COME. The optimized values to obtain a 98.3% yield of methyl ester were as follows: methanol/oil molar ratio of 6:1, catalyst concentration of 0.97% (w/w), temperature of 63.8 °C, and speed of 797 rpm. The physicochemical properties of COME were measured in accordance with ASTM D6751. The friction and wear properties of COME and its blends with petroleum diesel were tested using a four-ball wear testing machine. The tribological characteristics of COME as a new biofuel were assessed. COME displayed good lubricity with a low coefficient of friction and wear scar diameter. The coefficient of friction of pure COME (COME100) was lower than that of pure petroleum diesel (DL100) and COME blends with petrol diesel (COME10, COME20, and COME50). The average coefficient of friction of COME 100 was lower than that of DL100, COME10, COME20, and COME50 by 28.06%, 19.49%, 7.49%, and 3.65%, respectively. The wear scar diameter of COME100 for the tested ball was lower than that of DL100, COME10, COME20, and COME50 by 47.6%, 33.3%, 32.1%, and 21.42%, respectively. The worn surfaces of the tested balls were examined by scanning electron microscopy, and the results were presented in this paper.
first_indexed 2024-03-06T05:50:05Z
format Article
id um.eprints-20061
institution Universiti Malaya
last_indexed 2024-03-06T05:50:05Z
publishDate 2019
publisher Elsevier
record_format dspace
spelling um.eprints-200612019-01-18T02:01:57Z http://eprints.um.edu.my/20061/ Production optimization and tribological characteristics of cottonseed oil methyl ester Jamshaid, Muhammad Masjuki, Haji Hassan Kalam, Md. Abul Zulkifli, Nurin Wahidah Mohd Arslan, Ahmed Alwi, Azham Khuong, Leang So Alabdulkarem, Abdullah Syahir, A.Z. TJ Mechanical engineering and machinery This paper presented experimental results to evaluate the optimization of production parameters through response surface methodology. These parameters significantly affected the yield of cottonseed oil methyl ester (COME). The input variables for the production of methyl ester from cottonseed oil were methanol/oil molar ratio, concentration of catalyst, temperature, and stirring speed. The response or output variable was the yield of methyl ester. The fatty acid methyl ester composition of COME (biodiesel) was obtained using a gas chromatography (GC) analyzer. BS EN 14103:2011 was the standard used to analyze the fatty acid methyl ester. The derived mathematical model was statistically accurate to predict the optimum value of COME. The optimized values to obtain a 98.3% yield of methyl ester were as follows: methanol/oil molar ratio of 6:1, catalyst concentration of 0.97% (w/w), temperature of 63.8 °C, and speed of 797 rpm. The physicochemical properties of COME were measured in accordance with ASTM D6751. The friction and wear properties of COME and its blends with petroleum diesel were tested using a four-ball wear testing machine. The tribological characteristics of COME as a new biofuel were assessed. COME displayed good lubricity with a low coefficient of friction and wear scar diameter. The coefficient of friction of pure COME (COME100) was lower than that of pure petroleum diesel (DL100) and COME blends with petrol diesel (COME10, COME20, and COME50). The average coefficient of friction of COME 100 was lower than that of DL100, COME10, COME20, and COME50 by 28.06%, 19.49%, 7.49%, and 3.65%, respectively. The wear scar diameter of COME100 for the tested ball was lower than that of DL100, COME10, COME20, and COME50 by 47.6%, 33.3%, 32.1%, and 21.42%, respectively. The worn surfaces of the tested balls were examined by scanning electron microscopy, and the results were presented in this paper. Elsevier 2019 Article PeerReviewed Jamshaid, Muhammad and Masjuki, Haji Hassan and Kalam, Md. Abul and Zulkifli, Nurin Wahidah Mohd and Arslan, Ahmed and Alwi, Azham and Khuong, Leang So and Alabdulkarem, Abdullah and Syahir, A.Z. (2019) Production optimization and tribological characteristics of cottonseed oil methyl ester. Journal of Cleaner Production, 209. pp. 62-73. ISSN 0959-6526, DOI https://doi.org/10.1016/j.jclepro.2018.10.126 <https://doi.org/10.1016/j.jclepro.2018.10.126>. https://doi.org/10.1016/j.jclepro.2018.10.126 doi:10.1016/j.jclepro.2018.10.126
spellingShingle TJ Mechanical engineering and machinery
Jamshaid, Muhammad
Masjuki, Haji Hassan
Kalam, Md. Abul
Zulkifli, Nurin Wahidah Mohd
Arslan, Ahmed
Alwi, Azham
Khuong, Leang So
Alabdulkarem, Abdullah
Syahir, A.Z.
Production optimization and tribological characteristics of cottonseed oil methyl ester
title Production optimization and tribological characteristics of cottonseed oil methyl ester
title_full Production optimization and tribological characteristics of cottonseed oil methyl ester
title_fullStr Production optimization and tribological characteristics of cottonseed oil methyl ester
title_full_unstemmed Production optimization and tribological characteristics of cottonseed oil methyl ester
title_short Production optimization and tribological characteristics of cottonseed oil methyl ester
title_sort production optimization and tribological characteristics of cottonseed oil methyl ester
topic TJ Mechanical engineering and machinery
work_keys_str_mv AT jamshaidmuhammad productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT masjukihajihassan productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT kalammdabul productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT zulkiflinurinwahidahmohd productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT arslanahmed productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT alwiazham productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT khuongleangso productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT alabdulkaremabdullah productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester
AT syahiraz productionoptimizationandtribologicalcharacteristicsofcottonseedoilmethylester