Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment

The high-throughput experimentation technique was used to verify the testing conditions due to the effects of catalyst structure modifications and/or due to reaction parameter variation in parallel. In this paper, the design of experiment and catalytic results are discussed in the development of sel...

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Main Authors: Widi, Restu Kartiko, Hamid, Sharifah Bee Abd
Format: Article
Published: Universitas Gadjah Mada 2018
Subjects:
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author Widi, Restu Kartiko
Hamid, Sharifah Bee Abd
author_facet Widi, Restu Kartiko
Hamid, Sharifah Bee Abd
author_sort Widi, Restu Kartiko
collection UM
description The high-throughput experimentation technique was used to verify the testing conditions due to the effects of catalyst structure modifications and/or due to reaction parameter variation in parallel. In this paper, the design of experiment and catalytic results are discussed in the development of selective oxidation catalyst, to demonstrate the importance and versatility of such technology. It is used for the automated parallel testing of selective oxidation of propane to acrylic acid over some types of multi metal oxide catalysts. The catalysts used for performance test were Mo (molybdenum), cat-1 (unsupported Mo1V0.3Te0.23Nb0.125O), and cat-2 (supported Mo1V0.3Te0.23Nb0.125O). All catalysts were dried using spray drier. The effect of some reaction parameters, such as the amount of oxidant, presence of steam and reaction temperature was also investigated during the test. The configuration of the ‘nanoflow’ is shown to be suitable to screen catalytic performance. The results obtained gave very good reproducibility.
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spelling um.eprints-203762019-02-18T05:51:14Z http://eprints.um.edu.my/20376/ Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment Widi, Restu Kartiko Hamid, Sharifah Bee Abd Q Science (General) QD Chemistry TP Chemical technology The high-throughput experimentation technique was used to verify the testing conditions due to the effects of catalyst structure modifications and/or due to reaction parameter variation in parallel. In this paper, the design of experiment and catalytic results are discussed in the development of selective oxidation catalyst, to demonstrate the importance and versatility of such technology. It is used for the automated parallel testing of selective oxidation of propane to acrylic acid over some types of multi metal oxide catalysts. The catalysts used for performance test were Mo (molybdenum), cat-1 (unsupported Mo1V0.3Te0.23Nb0.125O), and cat-2 (supported Mo1V0.3Te0.23Nb0.125O). All catalysts were dried using spray drier. The effect of some reaction parameters, such as the amount of oxidant, presence of steam and reaction temperature was also investigated during the test. The configuration of the ‘nanoflow’ is shown to be suitable to screen catalytic performance. The results obtained gave very good reproducibility. Universitas Gadjah Mada 2018 Article PeerReviewed Widi, Restu Kartiko and Hamid, Sharifah Bee Abd (2018) Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment. Indonesian Journal of Chemistry, 18 (2). pp. 229-234. ISSN 1411-9420, DOI https://doi.org/10.22146/ijc.23959 <https://doi.org/10.22146/ijc.23959>. https://doi.org/10.22146/ijc.23959 doi:10.22146/ijc.23959
spellingShingle Q Science (General)
QD Chemistry
TP Chemical technology
Widi, Restu Kartiko
Hamid, Sharifah Bee Abd
Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment
title Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment
title_full Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment
title_fullStr Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment
title_full_unstemmed Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment
title_short Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment
title_sort steam influence and effect of oxidant amount on propane oxidation over multi metal oxide catalyst using high throughput experiment
topic Q Science (General)
QD Chemistry
TP Chemical technology
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AT hamidsharifahbeeabd steaminfluenceandeffectofoxidantamountonpropaneoxidationovermultimetaloxidecatalystusinghighthroughputexperiment