Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers

Intermetallic compounds (IMC) form during the metallurgical bonding processes when the interfaces involve solid metal and molten solder. Cobalt (Co) is a promising candidate to be used as under bump metallization (UBM) material, tin (Sn)-based solder alloying element, and transient liquid phase bond...

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Main Authors: Goh, Yingxin, Goh, Yi Sing, Lee, Ee Lynn, Ong, Meng Teck, Haseeb, A.S. Md. Abdul
Format: Article
Published: Springer 2018
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author Goh, Yingxin
Goh, Yi Sing
Lee, Ee Lynn
Ong, Meng Teck
Haseeb, A.S. Md. Abdul
author_facet Goh, Yingxin
Goh, Yi Sing
Lee, Ee Lynn
Ong, Meng Teck
Haseeb, A.S. Md. Abdul
author_sort Goh, Yingxin
collection UM
description Intermetallic compounds (IMC) form during the metallurgical bonding processes when the interfaces involve solid metal and molten solder. Cobalt (Co) is a promising candidate to be used as under bump metallization (UBM) material, tin (Sn)-based solder alloying element, and transient liquid phase bonding base metal. This work aims at studying the intermixing reaction in Co–Sn system from electroplated Co and Sn multilayers. Co–Sn couples were sequentially electroplated and reflowed at 400 °C for 1 and 4 h. The microstructure and composition of the phases formed at different reflow duration were characterized by field emission scanning electron microscopy (FESEM) coupled with energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). Mechanical properties of the IMC layers formed in the samples were characterized using the nanoindentation technique under quasi-static and continuous measurement modes. FESEM/EDX and XRD analysis showed a mixture of CoSn+CoSn2 phases was formed in the 1 h reflow sample. As reflow time was increased to 4 h, only CoSn phase was found. Pure CoSn phase exhibits high nanohardness of 9.51 GPa while the region with CoSn+CoSn2 phases gives nanohardness value of 6.83 GPa.
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spelling um.eprints-220092019-08-21T06:38:34Z http://eprints.um.edu.my/22009/ Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers Goh, Yingxin Goh, Yi Sing Lee, Ee Lynn Ong, Meng Teck Haseeb, A.S. Md. Abdul TJ Mechanical engineering and machinery Intermetallic compounds (IMC) form during the metallurgical bonding processes when the interfaces involve solid metal and molten solder. Cobalt (Co) is a promising candidate to be used as under bump metallization (UBM) material, tin (Sn)-based solder alloying element, and transient liquid phase bonding base metal. This work aims at studying the intermixing reaction in Co–Sn system from electroplated Co and Sn multilayers. Co–Sn couples were sequentially electroplated and reflowed at 400 °C for 1 and 4 h. The microstructure and composition of the phases formed at different reflow duration were characterized by field emission scanning electron microscopy (FESEM) coupled with energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). Mechanical properties of the IMC layers formed in the samples were characterized using the nanoindentation technique under quasi-static and continuous measurement modes. FESEM/EDX and XRD analysis showed a mixture of CoSn+CoSn2 phases was formed in the 1 h reflow sample. As reflow time was increased to 4 h, only CoSn phase was found. Pure CoSn phase exhibits high nanohardness of 9.51 GPa while the region with CoSn+CoSn2 phases gives nanohardness value of 6.83 GPa. Springer 2018 Article PeerReviewed Goh, Yingxin and Goh, Yi Sing and Lee, Ee Lynn and Ong, Meng Teck and Haseeb, A.S. Md. Abdul (2018) Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers. Journal of Materials Science: Materials in Electronics, 29 (7). pp. 5791-5798. ISSN 0957-4522, DOI https://doi.org/10.1007/s10854-018-8550-1 <https://doi.org/10.1007/s10854-018-8550-1>. https://doi.org/10.1007/s10854-018-8550-1 doi:10.1007/s10854-018-8550-1
spellingShingle TJ Mechanical engineering and machinery
Goh, Yingxin
Goh, Yi Sing
Lee, Ee Lynn
Ong, Meng Teck
Haseeb, A.S. Md. Abdul
Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers
title Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers
title_full Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers
title_fullStr Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers
title_full_unstemmed Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers
title_short Formation and characterization of intermetallic compounds in electroplated cobalt–tin multilayers
title_sort formation and characterization of intermetallic compounds in electroplated cobalt tin multilayers
topic TJ Mechanical engineering and machinery
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AT gohyising formationandcharacterizationofintermetalliccompoundsinelectroplatedcobalttinmultilayers
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AT ongmengteck formationandcharacterizationofintermetalliccompoundsinelectroplatedcobalttinmultilayers
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