Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The compl...
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| Format: | Article |
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Elsevier
2018
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| _version_ | 1796961607520092160 |
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| author | Bedowr, Noha Said Yahya, Rosiyah Farhan, Nesrain |
| author_facet | Bedowr, Noha Said Yahya, Rosiyah Farhan, Nesrain |
| author_sort | Bedowr, Noha Said |
| collection | UM |
| description | This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The complexes were further reacted between the product of the first reaction and 4,4′-bipyridine-2,2′-bipyridine respectively. The structural characterization techniques included elemental analysis, Fourier transformed infrared spectroscopy (FTIR), Ultra-violet–Visible (UV–Vis) spectroscopy, polarized optical microscopy, magnetic moment and thermogravimetric analysis. The structural and characterization results suggested that the synthesized complexes were binuclear and mononuclear covalent complexes of copper(II) with structural formulas [Cu2(η2-(OOCR)4](4,4′-bpy)2H2O] and [Cu(η1-(OOCR)2(2,2′-bpy) (4,4′-bpy)] respectively. |
| first_indexed | 2024-03-06T05:56:38Z |
| format | Article |
| id | um.eprints-22328 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:56:38Z |
| publishDate | 2018 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | um.eprints-223282019-09-13T03:21:26Z http://eprints.um.edu.my/22328/ Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties Bedowr, Noha Said Yahya, Rosiyah Farhan, Nesrain Q Science (General) QD Chemistry This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The complexes were further reacted between the product of the first reaction and 4,4′-bipyridine-2,2′-bipyridine respectively. The structural characterization techniques included elemental analysis, Fourier transformed infrared spectroscopy (FTIR), Ultra-violet–Visible (UV–Vis) spectroscopy, polarized optical microscopy, magnetic moment and thermogravimetric analysis. The structural and characterization results suggested that the synthesized complexes were binuclear and mononuclear covalent complexes of copper(II) with structural formulas [Cu2(η2-(OOCR)4](4,4′-bpy)2H2O] and [Cu(η1-(OOCR)2(2,2′-bpy) (4,4′-bpy)] respectively. Elsevier 2018 Article PeerReviewed Bedowr, Noha Said and Yahya, Rosiyah and Farhan, Nesrain (2018) Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties. Journal of Saudi Chemical Society, 22 (3). pp. 255-260. ISSN 1319-6103, DOI https://doi.org/10.1016/j.jscs.2017.08.003 <https://doi.org/10.1016/j.jscs.2017.08.003>. https://doi.org/10.1016/j.jscs.2017.08.003 doi:10.1016/j.jscs.2017.08.003 |
| spellingShingle | Q Science (General) QD Chemistry Bedowr, Noha Said Yahya, Rosiyah Farhan, Nesrain Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_full | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_fullStr | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_full_unstemmed | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_short | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_sort | structural characterization of copper ii tetradecanoate with 2 2 bipyridine and 4 4 bipyridine to study magnetic properties |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT bedowrnohasaid structuralcharacterizationofcopperiitetradecanoatewith22bipyridineand44bipyridinetostudymagneticproperties AT yahyarosiyah structuralcharacterizationofcopperiitetradecanoatewith22bipyridineand44bipyridinetostudymagneticproperties AT farhannesrain structuralcharacterizationofcopperiitetradecanoatewith22bipyridineand44bipyridinetostudymagneticproperties |