Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions
We present a biogenic method for the synthesis of palladium nanoparticle (PdNP)-modified by reducing graphene oxide sheets (rGO) in a one-pot strategy using Ficus carica fruit juice as the reducing agent. The synthesized material was well characterized by morphological and structural analyses, inclu...
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| Format: | Article |
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Public Library of Science
2018
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| author | Anasdass, Jaculin Raiza Kannaiyan, Pandian Raghavachary, Raghunathan Gopinath, Subash Chandra Bose Chen, Yeng |
| author_facet | Anasdass, Jaculin Raiza Kannaiyan, Pandian Raghavachary, Raghunathan Gopinath, Subash Chandra Bose Chen, Yeng |
| author_sort | Anasdass, Jaculin Raiza |
| collection | UM |
| description | We present a biogenic method for the synthesis of palladium nanoparticle (PdNP)-modified by reducing graphene oxide sheets (rGO) in a one-pot strategy using Ficus carica fruit juice as the reducing agent. The synthesized material was well characterized by morphological and structural analyses, including, Ultraviolet-Visible spectroscopy (UV-Vis), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and Transmission Electron Microscopy (TEM) and Raman spectroscopy. The results revealed that the PdNP modified GO are spherical in shape and estimated to be a dimension of ~0.16 nm. The PdNP/graphene exhibits a great catalytic activity in Suzuki cross-coupling reactions for the synthesis of biaryl compounds with various substrates under both aqueous and aerobic conditions. The catalyst can be recovered easily and is suitable for repeated use because it retains its original catalytic activity. The PdNP/rGO catalyst synthesized by an eco-friendly protocol was used for the Suzuki coupling reactions. The method offers a mild and effective substitute to the existing methods and may significantly contribute to green chemistry. |
| first_indexed | 2024-03-06T05:57:05Z |
| format | Article |
| id | um.eprints-22474 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:57:05Z |
| publishDate | 2018 |
| publisher | Public Library of Science |
| record_format | dspace |
| spelling | um.eprints-224742019-09-20T04:12:09Z http://eprints.um.edu.my/22474/ Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions Anasdass, Jaculin Raiza Kannaiyan, Pandian Raghavachary, Raghunathan Gopinath, Subash Chandra Bose Chen, Yeng QD Chemistry RK Dentistry TK Electrical engineering. Electronics Nuclear engineering TP Chemical technology We present a biogenic method for the synthesis of palladium nanoparticle (PdNP)-modified by reducing graphene oxide sheets (rGO) in a one-pot strategy using Ficus carica fruit juice as the reducing agent. The synthesized material was well characterized by morphological and structural analyses, including, Ultraviolet-Visible spectroscopy (UV-Vis), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and Transmission Electron Microscopy (TEM) and Raman spectroscopy. The results revealed that the PdNP modified GO are spherical in shape and estimated to be a dimension of ~0.16 nm. The PdNP/graphene exhibits a great catalytic activity in Suzuki cross-coupling reactions for the synthesis of biaryl compounds with various substrates under both aqueous and aerobic conditions. The catalyst can be recovered easily and is suitable for repeated use because it retains its original catalytic activity. The PdNP/rGO catalyst synthesized by an eco-friendly protocol was used for the Suzuki coupling reactions. The method offers a mild and effective substitute to the existing methods and may significantly contribute to green chemistry. Public Library of Science 2018 Article PeerReviewed Anasdass, Jaculin Raiza and Kannaiyan, Pandian and Raghavachary, Raghunathan and Gopinath, Subash Chandra Bose and Chen, Yeng (2018) Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions. PLoS ONE, 13 (2). e0193281. ISSN 1932-6203, DOI https://doi.org/10.1371/journal.pone.0193281 <https://doi.org/10.1371/journal.pone.0193281>. https://doi.org/10.1371/journal.pone.0193281 doi:10.1371/journal.pone.0193281 |
| spellingShingle | QD Chemistry RK Dentistry TK Electrical engineering. Electronics Nuclear engineering TP Chemical technology Anasdass, Jaculin Raiza Kannaiyan, Pandian Raghavachary, Raghunathan Gopinath, Subash Chandra Bose Chen, Yeng Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions |
| title | Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions |
| title_full | Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions |
| title_fullStr | Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions |
| title_full_unstemmed | Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions |
| title_short | Palladium nanoparticle-decorated reduced graphene oxide sheets synthesized using Ficus carica fruit extract: A catalyst for Suzuki cross-coupling reactions |
| title_sort | palladium nanoparticle decorated reduced graphene oxide sheets synthesized using ficus carica fruit extract a catalyst for suzuki cross coupling reactions |
| topic | QD Chemistry RK Dentistry TK Electrical engineering. Electronics Nuclear engineering TP Chemical technology |
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