The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution

In this study, carbon species were grown on the surface of Ni-impregnated powder activated carbon to form a novel hybrid carbon nanomaterial by chemical vapor deposition. The carbon nanomaterial was obtained by the precipitation of the methane elemental carbon atoms on the surface of the Ni catalyst...

Full description

Bibliographic Details
Main Authors: Alayan, Haiyam Mohammed, AlSaadi, Mohammed Abdulhakim, Das, Rasel, Abo-Hamad, Ali, Ibrahim, Rusul Khaleel, AlOmar, Mohammed Khaled, Hashim, Mohd Ali
Format: Article
Published: IWA Publishing 2018
Subjects:
_version_ 1796961658974765056
author Alayan, Haiyam Mohammed
AlSaadi, Mohammed Abdulhakim
Das, Rasel
Abo-Hamad, Ali
Ibrahim, Rusul Khaleel
AlOmar, Mohammed Khaled
Hashim, Mohd Ali
author_facet Alayan, Haiyam Mohammed
AlSaadi, Mohammed Abdulhakim
Das, Rasel
Abo-Hamad, Ali
Ibrahim, Rusul Khaleel
AlOmar, Mohammed Khaled
Hashim, Mohd Ali
author_sort Alayan, Haiyam Mohammed
collection UM
description In this study, carbon species were grown on the surface of Ni-impregnated powder activated carbon to form a novel hybrid carbon nanomaterial by chemical vapor deposition. The carbon nanomaterial was obtained by the precipitation of the methane elemental carbon atoms on the surface of the Ni catalyst. The physiochemical properties of the hybrid material were characterized to illustrate the successful growth of carbon species on the carbon substrate. The response surface methodology was used for the evaluation of adsorption parameters effect such as pH, adsorbent dose and contact time on the percentage removal of MB dye from aqueous solution. The optimum conditions were found to be pH = 11, adsorbent dose = 15 mg and contact time of 120 min. The material we prepared showed excellent removal efficiency of 96% for initial MB concentration of 50 mg/L. The adsorption of MB was described accurately by the pseudo-second-order model with R2 of 0.998 and qe of 163.93 (mg/g). The adsorption system showed the best agreement with Langmuir model with R2 of 0.989 and maximum adsorption capacity (Qm) of 250 mg/g.
first_indexed 2024-03-06T05:57:25Z
format Article
id um.eprints-22588
institution Universiti Malaya
last_indexed 2024-03-06T05:57:25Z
publishDate 2018
publisher IWA Publishing
record_format dspace
spelling um.eprints-225882019-09-26T07:26:31Z http://eprints.um.edu.my/22588/ The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution Alayan, Haiyam Mohammed AlSaadi, Mohammed Abdulhakim Das, Rasel Abo-Hamad, Ali Ibrahim, Rusul Khaleel AlOmar, Mohammed Khaled Hashim, Mohd Ali TA Engineering (General). Civil engineering (General) TP Chemical technology In this study, carbon species were grown on the surface of Ni-impregnated powder activated carbon to form a novel hybrid carbon nanomaterial by chemical vapor deposition. The carbon nanomaterial was obtained by the precipitation of the methane elemental carbon atoms on the surface of the Ni catalyst. The physiochemical properties of the hybrid material were characterized to illustrate the successful growth of carbon species on the carbon substrate. The response surface methodology was used for the evaluation of adsorption parameters effect such as pH, adsorbent dose and contact time on the percentage removal of MB dye from aqueous solution. The optimum conditions were found to be pH = 11, adsorbent dose = 15 mg and contact time of 120 min. The material we prepared showed excellent removal efficiency of 96% for initial MB concentration of 50 mg/L. The adsorption of MB was described accurately by the pseudo-second-order model with R2 of 0.998 and qe of 163.93 (mg/g). The adsorption system showed the best agreement with Langmuir model with R2 of 0.989 and maximum adsorption capacity (Qm) of 250 mg/g. IWA Publishing 2018 Article PeerReviewed Alayan, Haiyam Mohammed and AlSaadi, Mohammed Abdulhakim and Das, Rasel and Abo-Hamad, Ali and Ibrahim, Rusul Khaleel and AlOmar, Mohammed Khaled and Hashim, Mohd Ali (2018) The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution. Water Science and Technology, 77 (6). pp. 1714-1723. ISSN 0273-1223, DOI https://doi.org/10.2166/wst.2018.057 <https://doi.org/10.2166/wst.2018.057>. https://doi.org/10.2166/wst.2018.057 doi:10.2166/wst.2018.057
spellingShingle TA Engineering (General). Civil engineering (General)
TP Chemical technology
Alayan, Haiyam Mohammed
AlSaadi, Mohammed Abdulhakim
Das, Rasel
Abo-Hamad, Ali
Ibrahim, Rusul Khaleel
AlOmar, Mohammed Khaled
Hashim, Mohd Ali
The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution
title The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution
title_full The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution
title_fullStr The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution
title_full_unstemmed The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution
title_short The formation of hybrid carbon nanomaterial by chemical vapor deposition: an efficient adsorbent for enhanced removal of methylene blue from aqueous solution
title_sort formation of hybrid carbon nanomaterial by chemical vapor deposition an efficient adsorbent for enhanced removal of methylene blue from aqueous solution
topic TA Engineering (General). Civil engineering (General)
TP Chemical technology
work_keys_str_mv AT alayanhaiyammohammed theformationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT alsaadimohammedabdulhakim theformationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT dasrasel theformationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT abohamadali theformationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT ibrahimrusulkhaleel theformationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT alomarmohammedkhaled theformationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT hashimmohdali theformationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT alayanhaiyammohammed formationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT alsaadimohammedabdulhakim formationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT dasrasel formationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT abohamadali formationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT ibrahimrusulkhaleel formationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT alomarmohammedkhaled formationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution
AT hashimmohdali formationofhybridcarbonnanomaterialbychemicalvapordepositionanefficientadsorbentforenhancedremovalofmethylenebluefromaqueoussolution