The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation

Calcium phosphate coatings produced on the surface of Ti6Al4V by plasma electrolytic oxidation (PEO) using different concentrations of hydroxyapatite (HA) in a 0.12 M Na3PO4 (NAP) electrolyte solution was investigated. It was found that the amount of calcium phosphate particles infiltrated into the...

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Main Authors: Adeleke, Sakiru Adekunle, Ramesh, Singh, Bushroa, Abdul Razak, Ching, Yern Chee, Sopyan, Iis, Maleque, Md Abdul, Krishnasamy, Sivakumar, Chandran, Hari, Misran, Halina, Sutharsini, Ubenthiran
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Published: Elsevier 2018
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author Adeleke, Sakiru Adekunle
Ramesh, Singh
Bushroa, Abdul Razak
Ching, Yern Chee
Sopyan, Iis
Maleque, Md Abdul
Krishnasamy, Sivakumar
Chandran, Hari
Misran, Halina
Sutharsini, Ubenthiran
author_facet Adeleke, Sakiru Adekunle
Ramesh, Singh
Bushroa, Abdul Razak
Ching, Yern Chee
Sopyan, Iis
Maleque, Md Abdul
Krishnasamy, Sivakumar
Chandran, Hari
Misran, Halina
Sutharsini, Ubenthiran
author_sort Adeleke, Sakiru Adekunle
collection UM
description Calcium phosphate coatings produced on the surface of Ti6Al4V by plasma electrolytic oxidation (PEO) using different concentrations of hydroxyapatite (HA) in a 0.12 M Na3PO4 (NAP) electrolyte solution was investigated. It was found that the amount of calcium phosphate particles infiltrated into the coating layer as well as the thickness and the surface roughness of the coating increased with increasing HA concentration. The porosity of the ceramic coatings indicated an inverse relationship with the concentration of HA particles dispersed in the NAP solution. The result also demonstrates that higher scratch adhesive strength was achieved using 1.5 g/L HA solution, producing a critical load of 2099 mN, while 0 g/L HA only produced a critical load of 1247 mN. The adhesion becomes independent of thickness when the concentration of HA exceeds 1.5 g/L. The failure of the coating was characterized by large periodic hemispherical chipping, while intermittent delamination was noticed with the coating embedded with HA particles. This study demonstrate the viability of using PEO to produce a thin layer of HA ceramic coating on Ti6Al4V suitable for biomedical applications.
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spelling um.eprints-227022019-10-08T03:34:06Z http://eprints.um.edu.my/22702/ The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation Adeleke, Sakiru Adekunle Ramesh, Singh Bushroa, Abdul Razak Ching, Yern Chee Sopyan, Iis Maleque, Md Abdul Krishnasamy, Sivakumar Chandran, Hari Misran, Halina Sutharsini, Ubenthiran R Medicine TJ Mechanical engineering and machinery Calcium phosphate coatings produced on the surface of Ti6Al4V by plasma electrolytic oxidation (PEO) using different concentrations of hydroxyapatite (HA) in a 0.12 M Na3PO4 (NAP) electrolyte solution was investigated. It was found that the amount of calcium phosphate particles infiltrated into the coating layer as well as the thickness and the surface roughness of the coating increased with increasing HA concentration. The porosity of the ceramic coatings indicated an inverse relationship with the concentration of HA particles dispersed in the NAP solution. The result also demonstrates that higher scratch adhesive strength was achieved using 1.5 g/L HA solution, producing a critical load of 2099 mN, while 0 g/L HA only produced a critical load of 1247 mN. The adhesion becomes independent of thickness when the concentration of HA exceeds 1.5 g/L. The failure of the coating was characterized by large periodic hemispherical chipping, while intermittent delamination was noticed with the coating embedded with HA particles. This study demonstrate the viability of using PEO to produce a thin layer of HA ceramic coating on Ti6Al4V suitable for biomedical applications. Elsevier 2018 Article PeerReviewed Adeleke, Sakiru Adekunle and Ramesh, Singh and Bushroa, Abdul Razak and Ching, Yern Chee and Sopyan, Iis and Maleque, Md Abdul and Krishnasamy, Sivakumar and Chandran, Hari and Misran, Halina and Sutharsini, Ubenthiran (2018) The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation. Ceramics International, 44 (2). pp. 1802-1811. ISSN 0272-8842, DOI https://doi.org/10.1016/j.ceramint.2017.10.114 <https://doi.org/10.1016/j.ceramint.2017.10.114>. https://doi.org/10.1016/j.ceramint.2017.10.114 doi:10.1016/j.ceramint.2017.10.114
spellingShingle R Medicine
TJ Mechanical engineering and machinery
Adeleke, Sakiru Adekunle
Ramesh, Singh
Bushroa, Abdul Razak
Ching, Yern Chee
Sopyan, Iis
Maleque, Md Abdul
Krishnasamy, Sivakumar
Chandran, Hari
Misran, Halina
Sutharsini, Ubenthiran
The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation
title The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation
title_full The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation
title_fullStr The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation
title_full_unstemmed The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation
title_short The properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation
title_sort properties of hydroxyapatite ceramic coatings produced by plasma electrolytic oxidation
topic R Medicine
TJ Mechanical engineering and machinery
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