A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction
A luminescent edge-interlocked heteroleptic metallocage based on Cu3(pyrazolate)3 was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand wa...
| Hlavní autoři: | , , , , , , , |
|---|---|
| Médium: | Článek |
| Vydáno: |
Royal Society of Chemistry
2019
|
| Témata: |
| _version_ | 1825721961907486720 |
|---|---|
| author | Zhan, Shun-Ze Li, Jing-Hong Zhang, Guo-Hui Liu, Xiao-Wei Li, Mian Zheng, Ji Ng, Seik Weng Li, Dan |
| author_facet | Zhan, Shun-Ze Li, Jing-Hong Zhang, Guo-Hui Liu, Xiao-Wei Li, Mian Zheng, Ji Ng, Seik Weng Li, Dan |
| author_sort | Zhan, Shun-Ze |
| collection | UM |
| description | A luminescent edge-interlocked heteroleptic metallocage based on Cu3(pyrazolate)3 was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand was evidently responsible for the bathochromic shift of the optimal excitation. This work provides a heteroleptic strategy to regulate the interlocking fashion and photophysical mechanism of metallocages based on Cu3(pyrazolate)3. |
| first_indexed | 2024-03-06T05:58:21Z |
| format | Article |
| id | um.eprints-22903 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:21Z |
| publishDate | 2019 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | um.eprints-229032019-11-01T02:36:29Z http://eprints.um.edu.my/22903/ A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction Zhan, Shun-Ze Li, Jing-Hong Zhang, Guo-Hui Liu, Xiao-Wei Li, Mian Zheng, Ji Ng, Seik Weng Li, Dan Q Science (General) QD Chemistry A luminescent edge-interlocked heteroleptic metallocage based on Cu3(pyrazolate)3 was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand was evidently responsible for the bathochromic shift of the optimal excitation. This work provides a heteroleptic strategy to regulate the interlocking fashion and photophysical mechanism of metallocages based on Cu3(pyrazolate)3. Royal Society of Chemistry 2019 Article PeerReviewed Zhan, Shun-Ze and Li, Jing-Hong and Zhang, Guo-Hui and Liu, Xiao-Wei and Li, Mian and Zheng, Ji and Ng, Seik Weng and Li, Dan (2019) A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction. Chemical Communications, 55 (80). pp. 11992-11995. ISSN 1359-7345, DOI https://doi.org/10.1039/c9cc05236d <https://doi.org/10.1039/c9cc05236d>. https://doi.org/10.1039/c9cc05236d doi:10.1039/c9cc05236d |
| spellingShingle | Q Science (General) QD Chemistry Zhan, Shun-Ze Li, Jing-Hong Zhang, Guo-Hui Liu, Xiao-Wei Li, Mian Zheng, Ji Ng, Seik Weng Li, Dan A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
| title | A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
| title_full | A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
| title_fullStr | A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
| title_full_unstemmed | A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
| title_short | A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
| title_sort | luminescent edge interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT zhanshunze aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT lijinghong aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT zhangguohui aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT liuxiaowei aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT limian aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT zhengji aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT ngseikweng aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT lidan aluminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT zhanshunze luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT lijinghong luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT zhangguohui luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT liuxiaowei luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT limian luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT zhengji luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT ngseikweng luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction AT lidan luminescentedgeinterlockedprismaticheterolepticmetallocageassembledthroughaligandreplacementreaction |