Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer
In the title cadmium(II) complex, [Cd(C8H4O 5)(C14H14N4)(H2O)] n, the 5-hy-droxy-benzene-1,3-dicarboxyl-ate (5-OH-1,3-bdc) and 1,4-bis-(imidazol-1-ylmeth-yl)benzene (1,4,-bix) lig-ands bridge water-coordinated CdII atoms to generate a three-dimensional network. Two carboxyl-ate groups from different...
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| Format: | Article |
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International Union of Crystallography
2011
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| _version_ | 1825721977596280832 |
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| author | Zhou, Shi Li, Chuan-Bi Wang, Qing-Wei Ng, Seik Weng |
| author_facet | Zhou, Shi Li, Chuan-Bi Wang, Qing-Wei Ng, Seik Weng |
| author_sort | Zhou, Shi |
| collection | UM |
| description | In the title cadmium(II) complex, [Cd(C8H4O 5)(C14H14N4)(H2O)] n, the 5-hy-droxy-benzene-1,3-dicarboxyl-ate (5-OH-1,3-bdc) and 1,4-bis-(imidazol-1-ylmeth-yl)benzene (1,4,-bix) lig-ands bridge water-coordinated CdII atoms to generate a three-dimensional network. Two carboxyl-ate groups from different ligands function as O,O′-chelates, while two imidazole N atoms from different ligands coordinate in a monodentate fashion, and one water mol-ecule completes the seven-coordinate penta-gonal bipyramid around the CdII atom, in which the N atoms occupy the axial sites and the O atoms occupy the equatorial sites. The overall architecture is a twofold inter-penetrated CdSO4-type framework. The two crystallographically equivalent frameworks are linked by O-H⋯O hydrogen bonds between the water, hy-droxy and carboxyl-ate groups. © 2011 International Union of Crystallography. |
| first_indexed | 2024-03-06T05:58:35Z |
| format | Article |
| id | um.eprints-22985 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:35Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-229852019-11-14T02:34:43Z http://eprints.um.edu.my/22985/ Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer Zhou, Shi Li, Chuan-Bi Wang, Qing-Wei Ng, Seik Weng Q Science (General) QD Chemistry In the title cadmium(II) complex, [Cd(C8H4O 5)(C14H14N4)(H2O)] n, the 5-hy-droxy-benzene-1,3-dicarboxyl-ate (5-OH-1,3-bdc) and 1,4-bis-(imidazol-1-ylmeth-yl)benzene (1,4,-bix) lig-ands bridge water-coordinated CdII atoms to generate a three-dimensional network. Two carboxyl-ate groups from different ligands function as O,O′-chelates, while two imidazole N atoms from different ligands coordinate in a monodentate fashion, and one water mol-ecule completes the seven-coordinate penta-gonal bipyramid around the CdII atom, in which the N atoms occupy the axial sites and the O atoms occupy the equatorial sites. The overall architecture is a twofold inter-penetrated CdSO4-type framework. The two crystallographically equivalent frameworks are linked by O-H⋯O hydrogen bonds between the water, hy-droxy and carboxyl-ate groups. © 2011 International Union of Crystallography. International Union of Crystallography 2011 Article PeerReviewed Zhou, Shi and Li, Chuan-Bi and Wang, Qing-Wei and Ng, Seik Weng (2011) Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer. Acta Crystallographica Section C: Crystal Structure Communications, 67 (7). m224-m226. ISSN 0108-2701, DOI https://doi.org/10.1107/S010827011102083X <https://doi.org/10.1107/S010827011102083X>. https://doi.org/10.1107/S010827011102083X doi:10.1107/S010827011102083X |
| spellingShingle | Q Science (General) QD Chemistry Zhou, Shi Li, Chuan-Bi Wang, Qing-Wei Ng, Seik Weng Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer |
| title | Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer |
| title_full | Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer |
| title_fullStr | Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer |
| title_full_unstemmed | Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer |
| title_short | Poly[aqua[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ2-5-hydroxybenzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium(II)], a twofold interpenetrated CdSO4-like metal–organic polymer |
| title_sort | poly aqua μ2 1 4 bis imidazol 1 ylmethyl benzene κ2n3 n3 μ2 5 hydroxybenzene 1 3 dicarboxylato κ4o1 o1 o3 o3 cadmium ii a twofold interpenetrated cdso4 like metal organic polymer |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT zhoushi polyaquam214bisimidazol1ylmethylbenzenek2n3n3m25hydroxybenzene13dicarboxylatok4o1o1o3o3cadmiumiiatwofoldinterpenetratedcdso4likemetalorganicpolymer AT lichuanbi polyaquam214bisimidazol1ylmethylbenzenek2n3n3m25hydroxybenzene13dicarboxylatok4o1o1o3o3cadmiumiiatwofoldinterpenetratedcdso4likemetalorganicpolymer AT wangqingwei polyaquam214bisimidazol1ylmethylbenzenek2n3n3m25hydroxybenzene13dicarboxylatok4o1o1o3o3cadmiumiiatwofoldinterpenetratedcdso4likemetalorganicpolymer AT ngseikweng polyaquam214bisimidazol1ylmethylbenzenek2n3n3m25hydroxybenzene13dicarboxylatok4o1o1o3o3cadmiumiiatwofoldinterpenetratedcdso4likemetalorganicpolymer |