Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters
Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}...
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| Format: | Article |
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Elsevier
2011
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| author | Zhang, Zhen-Hua Wang, Hong-Mei Niu, Yun-Yin Wu, Ben-Lai Ng, Seik Weng Hou, Hong-Wei |
| author_facet | Zhang, Zhen-Hua Wang, Hong-Mei Niu, Yun-Yin Wu, Ben-Lai Ng, Seik Weng Hou, Hong-Wei |
| author_sort | Zhang, Zhen-Hua |
| collection | UM |
| description | Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}n (1) and {[WOS3Cu3Br(4,4-bipy)2.5]•3 (DMF)}n (2). Compound 1 exhibits a neutral 3D 3-fold interpenetrating motif and compound 2 possesses a neutral 3D 4-fold interpenetrating architecture. Both of them have been characterized by IR, elemental analysis, TGA, UV-vis, PXRD, and single-crystal X-ray diffraction. The results may provide fascinating insights into the usage of template effect on the construction of the cluster-based coordination polymers. © 2011 Elsevier B.V. All rights reserved. |
| first_indexed | 2024-03-06T05:58:35Z |
| format | Article |
| id | um.eprints-22987 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:35Z |
| publishDate | 2011 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | um.eprints-229872019-11-14T04:01:32Z http://eprints.um.edu.my/22987/ Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters Zhang, Zhen-Hua Wang, Hong-Mei Niu, Yun-Yin Wu, Ben-Lai Ng, Seik Weng Hou, Hong-Wei Q Science (General) QD Chemistry Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}n (1) and {[WOS3Cu3Br(4,4-bipy)2.5]•3 (DMF)}n (2). Compound 1 exhibits a neutral 3D 3-fold interpenetrating motif and compound 2 possesses a neutral 3D 4-fold interpenetrating architecture. Both of them have been characterized by IR, elemental analysis, TGA, UV-vis, PXRD, and single-crystal X-ray diffraction. The results may provide fascinating insights into the usage of template effect on the construction of the cluster-based coordination polymers. © 2011 Elsevier B.V. All rights reserved. Elsevier 2011 Article PeerReviewed Zhang, Zhen-Hua and Wang, Hong-Mei and Niu, Yun-Yin and Wu, Ben-Lai and Ng, Seik Weng and Hou, Hong-Wei (2011) Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters. Inorganic Chemistry Communications, 14 (11). pp. 1783-1787. ISSN 1387-7003, DOI https://doi.org/10.1016/j.inoche.2011.08.009 <https://doi.org/10.1016/j.inoche.2011.08.009>. https://doi.org/10.1016/j.inoche.2011.08.009 doi:10.1016/j.inoche.2011.08.009 |
| spellingShingle | Q Science (General) QD Chemistry Zhang, Zhen-Hua Wang, Hong-Mei Niu, Yun-Yin Wu, Ben-Lai Ng, Seik Weng Hou, Hong-Wei Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters |
| title | Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters |
| title_full | Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters |
| title_fullStr | Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters |
| title_full_unstemmed | Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters |
| title_short | Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters |
| title_sort | design and the cation templated self assembly on the moos3cu3 based supramolecular polymeric clusters |
| topic | Q Science (General) QD Chemistry |
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