Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]
In the title polymeric compound, [Cd(C9H12O 4)(C10H8N2)]n, the CdII atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3- dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjace...
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| Format: | Article |
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International Union of Crystallography
2011
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| _version_ | 1796961737983918080 |
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| author | Zhang, Xian-Fa Gao, Shan Ng, Seik Weng |
| author_facet | Zhang, Xian-Fa Gao, Shan Ng, Seik Weng |
| author_sort | Zhang, Xian-Fa |
| collection | UM |
| description | In the title polymeric compound, [Cd(C9H12O 4)(C10H8N2)]n, the CdII atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3- dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjacent CdII atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C - C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxylate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo-pentane ring. © Zhang et al. 2011. |
| first_indexed | 2024-03-06T05:58:36Z |
| format | Article |
| id | um.eprints-22989 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:36Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-229892019-11-14T04:34:30Z http://eprints.um.edu.my/22989/ Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] Zhang, Xian-Fa Gao, Shan Ng, Seik Weng Q Science (General) QD Chemistry In the title polymeric compound, [Cd(C9H12O 4)(C10H8N2)]n, the CdII atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3- dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjacent CdII atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C - C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxylate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo-pentane ring. © Zhang et al. 2011. International Union of Crystallography 2011 Article PeerReviewed Zhang, Xian-Fa and Gao, Shan and Ng, Seik Weng (2011) Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]. Acta Crystallographica Section E: Structure Reports Online, 67 (11). m1593-m1593. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536811042656 <https://doi.org/10.1107/S1600536811042656>. https://doi.org/10.1107/S1600536811042656 doi:10.1107/S1600536811042656 |
| spellingShingle | Q Science (General) QD Chemistry Zhang, Xian-Fa Gao, Shan Ng, Seik Weng Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] |
| title | Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] |
| title_full | Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] |
| title_fullStr | Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] |
| title_full_unstemmed | Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] |
| title_short | Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] |
| title_sort | poly μ2 4 4 bipyridine κ2n n μ2 2 2 dimethylcyclopentane 1 3 dicarboxylato κ4o1 o1 o3 o3 cadmium |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT zhangxianfa polym244bipyridinek2nnm222dimethylcyclopentane13dicarboxylatok4o1o1o3o3cadmium AT gaoshan polym244bipyridinek2nnm222dimethylcyclopentane13dicarboxylatok4o1o1o3o3cadmium AT ngseikweng polym244bipyridinek2nnm222dimethylcyclopentane13dicarboxylatok4o1o1o3o3cadmium |