(Z)-5-Benzenecarbothioyl-1,11-dimethyl-6-phenyl-5H-dibenzo[d,f][1,3]diazepine
The sevenmembered ring in the title compound, C28H 22N2S, has a twocoordinate N atom as well as a threecoordinate N atom. The ring adopts a boatshaped conformation with two C atoms of one methylphenyl ring as the stern and the threecoordinate N atom as the prow. The N,N-dimethylethanethioamide fragm...
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| Format: | Article |
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International Union of Crystallography
2011
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| Summary: | The sevenmembered ring in the title compound, C28H 22N2S, has a twocoordinate N atom as well as a threecoordinate N atom. The ring adopts a boatshaped conformation with two C atoms of one methylphenyl ring as the stern and the threecoordinate N atom as the prow. The N,N-dimethylethanethioamide fragment is nearly planar (r.m.s. deviation = 0.049 Å); the phenyl ring of the benzenecarbothioyl unit connected to the threecoordinate N atom is aligned at 83.72 (4)° with respect to the mean plane of this fragment. Weak intermolecular C -H⋯S hydrogen bonding is present in the crystal structure. |
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