3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one

3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one

In the title compound, C18H17Br2NOS 2, the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional...

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Bibliographic Details
Main Authors: Zukerman-Schpector, Julio, Olivato, Paulo R., Cerqueira Jr, Carlos R., Contieri, Bruna, Ng, Seik Weng, Tiekink, Edward R.T.
Format: Article
Published: International Union of Crystallography 2013
Subjects:
Q Science (General)
QD Chemistry
Description
Summary:In the title compound, C18H17Br2NOS 2, the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supramolecular chains along the b axis sustained by C-H⋯O interactions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C-H⋯Br and C-H⋯π interactions.

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