3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one
In the title compound, C18H17Br2NOS 2, the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional...
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| Format: | Article |
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International Union of Crystallography
2013
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| _version_ | 1796961749393473536 |
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| author | Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R.T. |
| author_facet | Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R.T. |
| author_sort | Zukerman-Schpector, Julio |
| collection | UM |
| description | In the title compound, C18H17Br2NOS 2, the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supramolecular chains along the b axis sustained by C-H⋯O interactions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C-H⋯Br and C-H⋯π interactions. |
| first_indexed | 2024-03-06T05:58:46Z |
| format | Article |
| id | um.eprints-23063 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:46Z |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-230632019-11-19T08:05:15Z http://eprints.um.edu.my/23063/ 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R.T. Q Science (General) QD Chemistry In the title compound, C18H17Br2NOS 2, the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supramolecular chains along the b axis sustained by C-H⋯O interactions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C-H⋯Br and C-H⋯π interactions. International Union of Crystallography 2013 Article PeerReviewed Zukerman-Schpector, Julio and Olivato, Paulo R. and Cerqueira Jr, Carlos R. and Contieri, Bruna and Ng, Seik Weng and Tiekink, Edward R.T. (2013) 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one. Acta Crystallographica Section E: Structure Reports Online, 69 (4). o556-o556. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536813006995 <https://doi.org/10.1107/S1600536813006995>. https://doi.org/10.1107/S1600536813006995 doi:10.1107/S1600536813006995 |
| spellingShingle | Q Science (General) QD Chemistry Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R.T. 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
| title | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
| title_full | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
| title_fullStr | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
| title_full_unstemmed | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
| title_short | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
| title_sort | 3 3 bis 4 bromophenylsulfanyl 1 methylpiperidin 2 one |
| topic | Q Science (General) QD Chemistry |
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