Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate
The Zn II atom in the title complex, [Zn(C 6H 4O 8S 2)(H 2O) 5] ·5(H 2O), is coordinated by five water mol-ecules and an O atom of a 4,6-dihy-droxy-benzene-1,3-disulfonate dianion. The coord-ination geometry is distorted octa-hedral, with the Zn-O sulfonate bond relatively long compared to the Zn-O...
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| Format: | Article |
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International Union of Crystallography
2012
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| _version_ | 1825721994112401408 |
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| author | Zhu, Zhi-Biao Gao, Shan Ng, Seik Weng Tiekink, Edward R.T. |
| author_facet | Zhu, Zhi-Biao Gao, Shan Ng, Seik Weng Tiekink, Edward R.T. |
| author_sort | Zhu, Zhi-Biao |
| collection | UM |
| description | The Zn II atom in the title complex, [Zn(C 6H 4O 8S 2)(H 2O) 5] ·5(H 2O), is coordinated by five water mol-ecules and an O atom of a 4,6-dihy-droxy-benzene-1,3-disulfonate dianion. The coord-ination geometry is distorted octa-hedral, with the Zn-O sulfonate bond relatively long compared to the Zn-O water bonds. The coordinated and lattice water mol-ecules inter-act with each other and with the hy-droxy groups and sulfonate ligand through O-H⋯O hydrogen bonds, generating a tightly held three-dimensional network. |
| first_indexed | 2024-03-06T05:58:50Z |
| format | Article |
| id | um.eprints-23087 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:50Z |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-230872019-11-22T04:13:01Z http://eprints.um.edu.my/23087/ Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate Zhu, Zhi-Biao Gao, Shan Ng, Seik Weng Tiekink, Edward R.T. Q Science (General) QD Chemistry The Zn II atom in the title complex, [Zn(C 6H 4O 8S 2)(H 2O) 5] ·5(H 2O), is coordinated by five water mol-ecules and an O atom of a 4,6-dihy-droxy-benzene-1,3-disulfonate dianion. The coord-ination geometry is distorted octa-hedral, with the Zn-O sulfonate bond relatively long compared to the Zn-O water bonds. The coordinated and lattice water mol-ecules inter-act with each other and with the hy-droxy groups and sulfonate ligand through O-H⋯O hydrogen bonds, generating a tightly held three-dimensional network. International Union of Crystallography 2012 Article PeerReviewed Zhu, Zhi-Biao and Gao, Shan and Ng, Seik Weng and Tiekink, Edward R.T. (2012) Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate. Acta Crystallographica Section E: Structure Reports Online, 68 (4). m492-m493. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536812012317 <https://doi.org/10.1107/S1600536812012317>. https://doi.org/10.1107/S1600536812012317 doi:10.1107/S1600536812012317 |
| spellingShingle | Q Science (General) QD Chemistry Zhu, Zhi-Biao Gao, Shan Ng, Seik Weng Tiekink, Edward R.T. Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate |
| title | Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate |
| title_full | Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate |
| title_fullStr | Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate |
| title_full_unstemmed | Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate |
| title_short | Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate |
| title_sort | pentaaqua 4 6 dihydroxybenzene 1 3 disulfonato κo1 zinc pentahydrate |
| topic | Q Science (General) QD Chemistry |
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